4-Cyano-1-(4-nitrobenzyl)pyridinium bis(2-thioxo-1,3-dithiole-4,5-dithiolato-κ2S4,S5)nickelate(III)

被引：0
|
作者：
Li, Kai-Hui [1 ]
Lei, Qing-Duo [1 ]
Mei, Chong-Zhen [1 ]
机构：
[1] N China Univ Water Conservancy & Elect Power, Inst Environm & Municipal Engn, Zhengzhou 450011, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词：
D O I：
10.1107/S1600536810037426
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title salt, (C13H10N3O2)[Ni(C3S5)(2)], the Ni-III cation is S,S'-chelated by two 2-thioxo-1,3-dithiole-4,5-dithiolate anions in a distorted square-planar geometry. The complex anion is approximately planar with a maximum deviation of 0.097 (1) angstrom. In the 1-(4-nitrobenzyl)-4-cyanopyridinium cation, the pyridine ring is twisted at a dihedral angle of 73.84 (16)degrees with respect to the benzene ring. pi-pi stacking is observed between nearly parallel [dihedral angle = 4.71 (7)degrees] dithiole and benzene rings, the centroid-centroid distance being 3.791 (2) angstrom.
引用
收藏
页码：M1311 / U1301
页数：11
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