1,3-Bis(2,4,6-trimethylphenyl)-3H-imidazol-1-ium tetraoxidorhenate(VII)

被引:0
|
作者
Landman, Marile [1 ]
van der Westhuizen, Belinda [1 ]
Bezuidenhout, Daniela I. [1 ]
Liles, David C. [1 ]
机构
[1] Univ Pretoria, Dept Chem, ZA-0028 Hatfield, South Africa
基金
新加坡国家研究基金会;
关键词
data-to-parameter ratio = 15.1; mean σ(C-C) = 0.006 Å; R factor = 0.033; single-crystal X-ray study; T = 293 K; wR factor = 0.083;
D O I
10.1107/S1600536811050677
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, (C21H25N2)[ReO4], was formed as the unexpected product in an attempted synthesis of a rhenium(I)-N-heterocyclic carbene (NHC) complex. The compound has crystallographic mirror symmetry with both the cation and the tetrahedral anion located across a mirror plane. The cation and anion are linked by a C-H center dot center dot center dot O hydrogen bond.
引用
收藏
页码:M1897 / U1195
页数:8
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