Isolation of two geometrical isomers of bis(mu-acetato)(mu-oxo)diiron(III) complexes with tridentate ligands and their activities for functionalization of cyclohexane in the presence of hydrogen peroxide

被引：12

作者：

Ito, S

Okuno, T

Matsushima, H

Tokii, T

Nishida, Y

机构：

[1] YAMAGATA UNIV, FAC SCI, DEPT CHEM, YAMAGATA 990, JAPAN

[2] SAGA UNIV, FAC SCI & ENGN, DEPT CHEM, SAGA 840, JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 21期

关键词：

D O I：

10.1039/dt9960004037

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two geometrical isomers of bis(mu-acetato)(mu-oxo)diiron(III) complexes with tridentate ligands were isolated and characterized by X-ray crystallography and their activities for cyclohexane functionalization in the presence of hydrogen peroxide examined.

引用

页码：4037 / 4039

页数：3

共 31 条

[11] SYNTHESIS AND CHARACTERIZATION OF BIS(MU-OXO)DIMANGANESE(III,III), BIS(MU-OXO)DIMANGANESE(III,IV), AND BIS(MU-OXO)DIMANGANESE(IV,IV) COMPLEXES WITH LIGANDS RELATED TO N,N'-BIS(2-PYRIDYLMETHYL)-1,2-ETHANEDIAMINE (BISPICEN)
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INORGANIC CHEMISTRY, 1994, 33 (18) : 4105 - 4111
[12] MODELS OF THE OXIDIZED FORMS OF POLYIRON OXO PROTEINS - SYNTHETIC ROUTES TO (MU-OXO)BIS(MU-CARBOXYLATO)DIIRON(III) COMPLEXES WITH NEUTRAL MONODENTATE AND BIDENTATE CAPPING LIGANDS
TAFT, KL
MASSCHELEIN, A
LIU, SC
LIPPARD, SJ
GARFINKELSHWEKY, D
BINO, A
INORGANICA CHIMICA ACTA, 1992, 198 : 627 - 631
[13] EFFECTS OF A BRIDGING DICARBOXYLATE LIGAND ON THE SYNTHESIS AND PHYSICAL-PROPERTIES OF (MU-OXO)BIS(MU-CARBOXYLATO)DIIRON(III) COMPLEXES
BEER, RH
TOLMAN, WB
BOTT, SG
LIPPARD, SJ
INORGANIC CHEMISTRY, 1991, 30 (09) : 2082 - 2092
[14] SINGLE-CRYSTAL ABSORPTION-SPECTROSCOPY OF BINUCLEAR COMPLEXES OF IRON(III) AND MANGANESE(III) WITH THE MU-OXO-BIS(MU-ACETATO)DIMETAL CORE
PELLETIER, Y
REBER, C
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1995, 73 (02): : 249 - 254
[15] NMR kinetic study of ligand exchange on a (mu-oxo)bis(mu-acetato)diruthenium(III) complex. A special kinetic case of introduction of a more labile ligand
Santos, JM
Cipriano, C
Faria, RB
FigueroaVillar, JD
CANADIAN JOURNAL OF CHEMISTRY, 1997, 75 (06) : 890 - 898
[16] SYNTHESIS, STRUCTURE, AND REACTIVITY OF (MU-OXO)BIS(MU-CARBOXYLATO)DIIRON(III) COMPLEXES OF A DINUCLEATING DICARBOXYLATE LIGAND, STABLE MODELS FOR NONHEME DIIRON PROTEIN CORES
WATTON, SP
MASSCHELEIN, A
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LIPPARD, SJ
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (12) : 5196 - 5205
[17] Synthesis, crystal structure and redox properties of mu-oxo-bis(mu-acetato)diruthenium(III) complexes having 2,2'-bipyridine and imidazole bases as terminal ligands
Sudha, C
Chakravarty, AR
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (15): : 3289 - 3292
[18] IMPORTANT ROLE OF TETRAHYDROFURAN RING IN ACTIVATION OF HYDROGEN-PEROXIDE IN THE PRESENCE OF BINUCLEAR IRON(III) COMPLEXES WITH LINEAR MU-OXO BRIDGE
NISHIDA, Y
OKUNO, T
ITO, S
HARADA, A
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MATSUSHIMA, H
TOKII, T
CHEMISTRY LETTERS, 1995, (10) : 885 - 886
[19] SYNTHESIS, STRUCTURE AND REDOX PROPERTIES OF (MU-OXO)BIS(MU-CARBOXYLATO)DIRUTHENIUM(III) COMPLEXES CONTAINING 3 DIFFERENT TERMINAL LIGANDS
SYAMALA, A
CHAKRAVARTY, AR
POLYHEDRON, 1993, 12 (03) : 273 - 278
[20] A GENERAL-METHOD FOR ASSEMBLING (MU-OXO)BIS(MU-CARBOXYLATO)DIIRON(III) COMPLEXES WITH LABILE TERMINAL SITES USING A BRIDGING DICARBOXYLATE LIGAND
BEER, RH
TOLMAN, WB
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INORGANIC CHEMISTRY, 1989, 28 (26) : 4557 - 4559

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