Detection of Fe3+ ions in aqueous environment using fluorescent carbon quantum dots synthesized from endosperm of Borassus flabellifer

被引:69
|
作者
Nagaraj, Murugan [1 ]
Ramalingam, Srinivasan [1 ]
Murugan, Chandran [2 ]
Aldawood, S. [3 ]
Jin, Jun-O [4 ,5 ]
Choi, Inho [4 ,5 ]
Kim, Myunghee [1 ,5 ]
机构
[1] Yeungnam Univ, Dept Food Sci & Technol, Gyongsan 38541, Gyeongsangbuk D, South Korea
[2] SRM Inst Sci & Technol, Kattankulathur 603203, Tamil Nadu, India
[3] King Saud Univ, Coll Sci, Dept Phys & Astron, POB 2455, Riyadh 11451, Saudi Arabia
[4] Yeungnam Univ, Dept Med Biotechnol, Gyongsan 38541, Gyeongsangbuk D, South Korea
[5] Yeungnam Univ, Res Inst Cell Culture, Gyongsan 38541, Gyeongsangbuk D, South Korea
关键词
carbon quantum dots; ferric ions (Fe3+); fluorescent sensor; green synthesis; ice apple; metal contamination; SELECTIVE DETECTION; SENSING PLATFORM; FACILE SYNTHESIS; GREEN SYNTHESIS; GRAPHENE; NANODOTS; PROBES;
D O I
10.1016/j.envres.2022.113273
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Natural products derived carbon quantum dots (CQDs) catch huge attention owing to their distinctive properties of smaller size, water dispersibility, high photostability, lower cost, tunable emission, biocompatibility, least toxicity, electrical conductivity, optical and catalytic properties, and easy modification. Herein high fluorescent CQDs were prepared using Borassus flabellifer (ice apple) as a carbon source utilizing the simplistic one-step hydrothermal method. The prepared CQDs possessed excellent photoluminescence, high photostability, and stability in an aqueous solution and harbored large of quantum yield and strong stability in high pH conditions with the characteristic strong blue fluorescence emission. With these superior properties, the CQDs have been used as sensing probes for the detection of Fe3+ ions having excellent selectivity and sensitivity with a 2.01 mu M limit of detection. The CQDs decorated probe was found effective in detecting Fe3+ ions in the tap and drinking mineral water, suggesting the applicability of the prepared sensor. The developed sensor exhibited advantages, including simple, low-cost, label-free, rapid, and good sensitivity and selectivity towards Fe3+ ions, with a great application for detection of such ions in real water.
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页数:8
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