Flower-like CuO microspheres with enhanced catalytic performance for dimethyldichlorosilane synthesis

被引：42

作者：

Zhang, Zailei ^{[1
,2
]}

Che, Hongwei ^{[1
]}

Wang, Yingli ^{[1
]}

Gao, Jiajian ^{[1
]}

She, Xilin ^{[2
]}

Sun, Jin ^{[2
]}

Zhong, Ziyi ^{[3
]}

Su, Fabing ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China

[2] Qingdao Univ, Coll Chem & Environm Engn, Qingdao 266071, Peoples R China

[3] ASTAR, Inst Chem Engn & Sci, Singapore 627833, Singapore

来源：

RSC ADVANCES | 2012年 / 2卷 / 06期

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

MECHANISM; METHYLCHLOROSILANES; FABRICATION; CU3SI; NANOSTRUCTURES; NANOWIRES; KINETICS; SILICON; REACTOR; PHASE;

D O I：

10.1039/c2ra00923d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Flower-like CuO microspheres synthesized by a facile hydrothermal method were found to be an effective catalyst for the Rochow reaction with a higher dimethyldichlorosilane selectivity and Si conversion because of the enhanced formation of an active CuxSi phase and mass transport.

引用

页码：2254 / 2256

页数：3

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