N-(4-bromophenylsulfonyl)-2,2,2-trimethylacetamide

被引：0
|
作者：
Gowda, B. Thimme [1 ]
Foro, Sabine [2 ]
Nirmala, P. G. [1 ]
Sowmya, B. P. [1 ]
Fuess, Hartmut [2 ]
机构：
[1] Mangalore Univ, Dept Chem, Mangalagangothri 574199, Karnataka, India
[2] TH Darmstadt, Inst Mat Sci, D-64287 Darmstadt, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词：
D O I：
10.1107/S1600536808019375
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The conformations of the N-H and C=O bonds in the SO2-NH-CO-C group of the title compound (N4BPSTMAA), C11H14BrNO3S, are trans to each other, similar to what is observed in N-(4-chlorophenylsulfonyl)-2,2,2-trimethylacetamide (N4CPSTMAA) and 2,2,2-trimethyl-N-(4-methylphenylsulfonyl) acetamide (N4MPSTMAA). The bond parameters in N4BPSTMAA are similar to those in N4CPSTMAA, N4MPSTMAA, N-aryl-2,2,2-trimethylacetamides and 4-bromobenzenesulfonamide. The benzene ring and the SO2-NH-CO-C group in N4BPSTMAA form a dihedral angle of 82.8 (1)degrees, comparable with the values of 82.2 (1)degrees in N4CPSTMAA and 71.2 (1)degrees in N4MPSTMAA. N-H center dot center dot center dot O hydrogen bonds form a centrosymmetric ring characterized by an R-2(2)(8) motif.
引用
收藏
页码：O1389 / U1331
页数：9
相关论文
共 50 条
  • [41] Low-temperature crystallization and structure determination of N-(trifluoromethyl)formamide, N-(2,2,2-trifluoroethyl)formamide and 2,2,2-trifluoroethyl isocyanide
    Perpetuo, G.J.
    Buschmann, J.
    Luger, P.
    Lentz, D.
    Dreissig, D.
    Acta Crystallographica, Section B: Structural Science, 1999, 55 (pt 1):
  • [42] Reactions of N-(2,2,2-trichloroethylidene)- and N-(2,2-dichloro-2-phenylethylidene)arenesulfonamides with biuret
    G. N. Rozentsveig
    A. V. Popov
    I. B. Rozentsveig
    G. G. Levkovskaya
    Russian Journal of Organic Chemistry, 2008, 44 : 1486 - 1489
  • [43] Reactions of N-(2,2,2-trichloroethylidene)- and N-(2,2-dichloro-2-phenylethylidene)arenesulfonamides with biuret
    Rozentsveig, G. N.
    Popov, A. V.
    Rozentsveig, I. B.
    Levkovskaya, G. G.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2008, 44 (10) : 1486 - 1489
  • [44] Synthesis of N-arylsulfonylimidazolidine-4-ones from N-(2,2,2-trichloroethylidene)arenesulfonamides and monochloroacetamide
    Rozentsveig, IB
    Evstaf'eva, IT
    Sarapulova, GI
    Levkovskaya, GG
    Aizina, JA
    ARKIVOC, 2003, : 45 - 51
  • [45] Synthesis of N-(2,2-Dichlorovinyl)arenesulfonamides by Dehydrochlorination of N-(2,2,2-Trichloroethyl)arenesulfonamides
    Chernysheva, G. N.
    Nikitin, I. V.
    Rozentsveig, I. B.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2018, 54 (05) : 789 - 791
  • [46] Synthesis of N-(2,2-Dichlorovinyl)arenesulfonamides by Dehydrochlorination of N-(2,2,2-Trichloroethyl)arenesulfonamides
    G. N. Chernysheva
    I. V. Nikitin
    I. B. Rozentsveig
    Russian Journal of Organic Chemistry, 2018, 54 : 789 - 791
  • [47] [N-(1-Azanidyl-2,2,2-trichloroethylidene)-2,2,2-trichloroethanimidamide]copper(II)
    Shikhaliyev, Namig G.
    Maharramov, Abel M.
    Muzalevskiy, Vasily M.
    Nenajdenko, Valentine G.
    Khrustalev, Victor N.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1220 - +
  • [48] Synthesis and Properties of N-(2,2,2-Trichloroethyl)-2-thiophenesulfonamides
    Yu. A. Aizina
    I. B. Rozentsveig
    G. G. Levkovskaya
    A. N. Mirskova
    Russian Journal of Organic Chemistry, 2003, 39 : 1334 - 1337
  • [49] Synthesis and properties of N-(2,2,2-trichloroethyl)-2-thiophenesulfonamides
    Aizina, YA
    Rozentsveig, IB
    Levkovskaya, GG
    Mirskova, AN
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2003, 39 (09) : 1334 - 1337
  • [50] Synthesis and Herbicidal Activity of Novel N-(2,2,2)-Trifluoroethylpyrazole Derivatives
    Ma, Hong-Ju
    Li, Yong-Hong
    Zhao, Qian-Fei
    Zhang, Tao
    Xie, Ru-Liang
    Mei, Xiang-Dong
    Ning, Jun
    JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2010, 58 (07) : 4356 - 4360
12345