Metal-catalyzed reactions for the C(sp2)-N bond formation: achievements of recent years

被引：27

作者：

Beletskaya, Irina P. ^{[1
]}

Averin, Alexei D. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Leninskie Gory 1,Stroenie 3, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL REVIEWS | 2021年 / 90卷 / 11期

关键词：

C-H AMINATION; BUCHWALD-HARTWIG AMINATION; CROSS-COUPLING REACTIONS; ADAMANTANE-CONTAINING AMINES; DIRECT OXIDATIVE AMINATION; EFFICIENT COPPER CATALYST; QUINOLINE N-OXIDES; ARYL HALIDES; ROOM-TEMPERATURE; CHAN-LAM;

D O I：

10.1070/RCR4999

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The review deals with the main catalytic methods for the C(sp(2))-N bond formation, including Buchwald-Hartwig palladium-catalyzed amination of aryl and heteroaryl halides, renaissance of the Ullmann chemistry, i.e., the application of catalysis by copper complexes to form the carbon-nitrogen bond, and Chan-Lam reactions of (hetero)arylboronic acids with amines. Also, oxidative amination with C-H activation, which has been booming during the last decade, is addressed. Particular attention is paid to achievements in the application of heterogenized catalysts. The bibliography includes 350 references.

引用

页码：1359 / 1396

页数：39

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