Solubility and complexation in the series of compounds of alkaline-earth and alkali metals

被引：1
|
作者：
Vasil'ev, VP [1 ]
机构：
[1] Ivanovo State Univ Chem Technol, Ivanovo, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2003年 / 29卷 / 10期
关键词：
Experimental Data; Physical Chemistry; Theoretical Result; Alkali Metal; Metal Cation;
D O I：
10.1023/A:1026011830397
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The solubility of salts with alkali and alkaline-earth metal cations and its dependence on the anion radius were discussed. The theoretical results were confirmed by experimental data on solubility. The stability of complexes in the Mg2+-Ba2+ series was considered depending on the ligand charge and radius. The revealed tendencies were explained in terms of the competition between solvent and ligand in solution for a central ion.
引用
收藏
页码：669 / 674
页数：6
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