Nitrogen-Rich Azoles as Ligand Spacers in Coordination Polymers

被引:71
|
作者
Bai, Shi-Qiang [1 ]
Young, David J. [3 ]
Hor, T. S. Andy [1 ,2 ]
机构
[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
[2] Agcy Sci Technol & Res, Inst Mat Res & Engn, Singapore 117602, Singapore
[3] Univ Brunei Darussalam, Fac Sci, BE-1410 Gadong, Brunei Darussal, Brunei
关键词
azoles; coordination polymers; nitrogen heterocycles; oligomers; supramolecules; METAL-ORGANIC FRAMEWORKS; TRINUCLEAR COPPER(II) COMPLEX; ANION-EXCHANGE PROPERTIES; CROSS-COUPLING REACTIONS; N-HETEROCYCLIC CARBENES; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; TRIPODAL LIGAND; SPIN-CROSSOVER; HYDROGEN STORAGE;
D O I
10.1002/asia.201000698
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
N-heterocycle-based ligands are versatile building-blocks for coordination oligomer and polymer assemblies of first-row transition metals. Herein, we review recent developments in the design and synthesis of some nitrogen-rich azole-based ligands, their assembly modes in coordination oligomers and polymers, and the potential applications of the resulting metallosupramolecules.
引用
收藏
页码:292 / 304
页数:13
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