Mid-infrared spectrum of [Ru(phen)3]2+*

被引：24
|
作者：
Omberg, KM
Schoonover, JR
Bernhard, S
Moss, JA
Treadway, JA
Kober, EM
Dyer, RB
Meyer, TJ
机构：
[1] Univ Calif Los Alamos Natl Lab, Chem Sci & Technol Div, Biosci & Biotechnol Grp CST4, Los Alamos, NM 87545 USA
[2] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA
来源：
INORGANIC CHEMISTRY | 1998年 / 37卷 / 14期
关键词：
D O I：
10.1021/ic971554e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Time-resolved infrared spectra in the fingerprint region (1300-1700 cm(-1)) are reported for the metal-to-ligand charge-transfer (MLCT) excited state(s) of [Ru(phen)(3)](2+)* and [Os(phen)(DAS)(2)](2+)* (phen is 1,10-phenanthroline; DAS is 1,2-bis(diphenylarsino)ethane) in acetonitrile-d(3) at 298 K. The spectra are assigned by comparison to electrochemically generated [Ru-III(phen)(3)](3+) and [Ru-II(phen(.-))(phen)(2)](+). The data provide clear evidence for the localized description [Ru-III(phen(.-))(phen)(2)](2+)* on the similar to 100 ns time scale. They also give insight into electronic distribution in the excited state, aid in the interpretation of the time-resolved resonance Raman spectrum of [Ru(phen)(3)](2+)*, and suggest why measuring ground- and excited-state resonance Raman spectra of phen complexes is difficult.
引用
收藏
页码：3505 / 3508
页数：4
相关论文
共 50 条
  • [41] Variations of the mid-infrared emission spectrum in reflection nebulae
    Bregman, J
    Temi, P
    ASTROPHYSICAL JOURNAL, 2005, 621 (02): : 831 - 838
  • [42] IRTS observations of the mid-infrared spectrum of the zodiacal emission
    Ootsubo, T
    Onaka, T
    Yamamura, I
    Tanabé, T
    Roellig, TL
    Chan, KW
    Matsumoto, T
    SPACE INFRARED TELESCOPES AND RELATED SCIENCE, 2000, 25 (11): : 2163 - 2166
  • [43] Antiresonances in the Mid-Infrared Vibrational Spectrum of Functionalized Graphene
    Lapointe, Francois
    Rousseau, Bruno
    Aymong, Vincent
    Minh Nguyen
    Biron, Maxime
    Gaufres, Etienne
    Choubak, Saman
    Han, Zheng
    Bouchiat, Vincent
    Desjardins, Patrick
    Cote, Michel
    Martel, Richard
    JOURNAL OF PHYSICAL CHEMISTRY C, 2017, 121 (16): : 9053 - 9062
  • [44] The mid-infrared spectrum of the Galactic Center - a starburst nucleus
    Simpson, JP
    Witteborn, FC
    Cohen, M
    Price, SD
    CENTRAL PARSECS OF THE GALAXY, 1999, 186 : 527 - 535
  • [45] IRTS observation of the mid-infrared spectrum of the zodiacal emission
    T. Ootsubo
    T. Onaka
    I. Yamamura
    T. Tanabé
    T. L. Roellig
    K. -W. Chan
    T. Matsumoto
    Earth, Planets and Space, 1998, 50 : 507 - 511
  • [46] COMPARATIVE-STUDY OF SOLVENT EFFECTS ON THE RACEMIZATION OF [FE(PHEN)3]2+ AND [NI(PHEN)3]2+
    YAMAMOTO, M
    FUJIWARA, T
    YAMAMOTO, Y
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1979, (APR): : 190 - 190
  • [47] Synthesis, characterization, DNA-binding and photocleavage studies of [Ru(bpy)2(PPIP)]2+ and [Ru(phen)2(PPIP)]2+
    Tan, LF
    Chao, H
    Li, H
    Liu, YJ
    Sun, B
    Wei, W
    Ji, LN
    JOURNAL OF INORGANIC BIOCHEMISTRY, 2005, 99 (02) : 513 - 520
  • [48] Efficient calculation of the mid-infrared supercontinuum spectrum in As2S3 photonic crystal fibers
    Weiblen, R. J.
    Docherty, A.
    Menyuk, C. R.
    Shaw, L. B.
    Sanghera, J. S.
    Aggarwal, I. D.
    2013 IEEE PHOTONICS CONFERENCE (IPC), 2013, : 400 - 401
  • [49] Mid-infrared spectrum of the weakly bound complex CO2-SO2
    Osthoff, Hans D.
    Jager, Wolfgang
    MOLECULAR PHYSICS, 2006, 104 (18) : 2861 - 2869
  • [50] Mid-infrared spectrum of dilute holes in antiferromagnetic CuO2 layers
    Kleinberg, DS
    Chou, FC
    Birgeneau, RJ
    Kastner, MA
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2000, 69 (03) : 749 - 753
12345