Synthesis of metal sulfide nanomaterials via thermal decomposition of single-source precursors

被引:98
|
作者
Jen-La Plante, Ilan [1 ,2 ]
Zeid, Tahani W. [2 ]
Yang, Peidong [1 ,2 ]
Mokari, Taleb [1 ]
机构
[1] Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA
[2] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
关键词
SOLAR-CELLS; NANOWIRES; NANOCRYSTALS; GROWTH; CU2S; CHALCOCITE; CRYSTALS; NANORODS; CDS;
D O I
10.1039/c0jm00439a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this report, we present a synthetic method for the formation of cuprous sulfide (Cu(2)S) and lead sulfide (PbS) nanomaterials directly on substrates from the thermolysis of single-source precursors. We find that the final morphology and arrangement of the nanomaterials may be controlled through the concentration of the dissolved precursors and choice of solvent. One-dimensional (1-D) morphologies may also be grown onto substrates with the addition of a metal catalyst layer through solution-liquid-solid (SLS) growth. These synthetic techniques may be expanded to other metal sulfide materials.
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页码:6612 / 6617
页数:6
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