Synthesis of metal sulfide nanomaterials via thermal decomposition of single-source precursors

被引:98
|
作者
Jen-La Plante, Ilan [1 ,2 ]
Zeid, Tahani W. [2 ]
Yang, Peidong [1 ,2 ]
Mokari, Taleb [1 ]
机构
[1] Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA
[2] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
关键词
SOLAR-CELLS; NANOWIRES; NANOCRYSTALS; GROWTH; CU2S; CHALCOCITE; CRYSTALS; NANORODS; CDS;
D O I
10.1039/c0jm00439a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this report, we present a synthetic method for the formation of cuprous sulfide (Cu(2)S) and lead sulfide (PbS) nanomaterials directly on substrates from the thermolysis of single-source precursors. We find that the final morphology and arrangement of the nanomaterials may be controlled through the concentration of the dissolved precursors and choice of solvent. One-dimensional (1-D) morphologies may also be grown onto substrates with the addition of a metal catalyst layer through solution-liquid-solid (SLS) growth. These synthetic techniques may be expanded to other metal sulfide materials.
引用
收藏
页码:6612 / 6617
页数:6
相关论文
共 50 条
  • [1] Nanometric metal sulfide particles from the thermal decomposition of xanthate single-source precursors.
    Piquette, AP
    Apblett, AW
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 229 : U1041 - U1041
  • [2] An efficient method for the synthesis of nickel phosphide nanocrystals via thermal decomposition of single-source precursors
    Pan, Yuan
    Liu, Yunqi
    Liu, Chenguang
    [J]. RSC ADVANCES, 2015, 5 (16): : 11952 - 11959
  • [3] Transition Metal Polysulfide Complexes as Single-Source Precursors for Metal Sulfide Nanocrystals
    Beal, John H. L.
    Etchegoin, Pablo G.
    Tilley, Richard D.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (09): : 3817 - 3821
  • [4] Synthesis of heterometallic metal phosphides from single-source precursors
    Colson, Adam C.
    Rusakova, Irene
    Whitmire, Kenton H.
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 238
  • [5] Synthesis and characterization of single-source molecular precursors for the preparation of metal chalcogenides
    Vimal K. Jain
    [J]. Journal of Chemical Sciences, 2006, 118 : 547 - 552
  • [6] Synthesis and characterization of single-source molecular precursors for the preparation of metal chalcogenides
    Jain, Vimal K.
    [J]. JOURNAL OF CHEMICAL SCIENCES, 2006, 118 (06) : 547 - 552
  • [7] Synthesis of ternary sulfide nanomaterials using dithiocarbamate complexes as single source precursors
    Roffey, Anna
    Hollingsworth, Nathan
    Hogarth, Graeme
    [J]. NANOSCALE ADVANCES, 2019, 1 (08): : 3056 - 3066
  • [8] Single-source precursors to ternary silver indium sulfide materials
    Deivaraj, TC
    Park, JH
    Afzaal, M
    O'Brien, P
    Vittal, JJ
    [J]. CHEMICAL COMMUNICATIONS, 2001, (22) : 2304 - 2305
  • [9] Preparation of ultrafine chalcopyrite nanoparticles via the photochemical decomposition of molecular single-source precursors
    Nairn, Justin J.
    Shapiro, Pamela J.
    Twamley, Brendan
    Pounds, Tyler
    von Wandruszka, Ray
    Fletcher, T. Rick
    Williams, Mark
    Wang, Chongmin
    Norton, M. Grant
    [J]. NANO LETTERS, 2006, 6 (06) : 1218 - 1223
  • [10] Generalized synthesis of metal sulfide nanocrystals from single-source precursors: size, shape and chemical composition control and their properties
    Shen, Shuling
    Zhang, Yejun
    Peng, Long
    Xu, Bing
    Du, Yaping
    Deng, Manjiao
    Xu, Huarui
    Wang, Qiangbin
    [J]. CRYSTENGCOMM, 2011, 13 (14): : 4572 - 4579