Thienyl and thenyl alkyl disulfides: monomers and polymers

被引：2
|
作者：
Duchenet, V
Andrieu, CG
Catel, JM
Le Coustumer, G
Penneau, JF
Le Guillanton, G
Hapiot, P
Audebert, P
机构：
[1] Univ Caen, ISMRA, Lab Chim Mol & Thioorgan, CNRS,UMR 6507, F-14050 Caen, France
[2] Univ Catholique Ouest, CNRS, UMR 6501, Lab Electrochim Organ, F-49008 Angers, France
[3] Univ Paris 07, Electrochim Mol Lab, F-75251 Paris, France
[4] Univ Franche Comte, Chim Organ Lab, F-25030 Besancon, France
[5] Ctr Rech EDF, F-77250 Moret Sur Loing, France
来源：
JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE | 1998年 / 95卷 / 06期
关键词：
thiophene; disulfide; polymerization; passivation;
D O I：
10.1051/jcp:1998253
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Thienyl and thenyl alkyl disulfides are synthesized by reaction between a mercaptan and dialkylazodicarboxylate; the addition of a second mercaptan gives the unsymmetrical disulfide. The cyclic disulfide, dithieno[3,2-c:2',3'-e][1,2] dithiin is obtained from the 2,2'-dibromobithiophene. These thiophene derivatives including a second redox system are potential precursors for polymers. Chemical polymerization affords new materials.
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页码：1229 / 1233
页数：5
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