Runaway prevention in liquid-phase homogeneous semibatch reactors

被引：28
|
作者：
Molga, Eugeniusz J.
Lewak, Michal
Roel Westerterp, K.
机构：
[1] Warsaw Univ Technol, Dept Chem & Proc Engn, PL-00645 Warsaw, Poland
[2] Ramon Llull Univ, Inst Quim Sarria, Barcelona 08017, Spain
来源：
CHEMICAL ENGINEERING SCIENCE | 2007年 / 62卷 / 18-20期
关键词：
chemical reactors; heat transfer; homogeneous reactions; thermal runaway; reaction engineering; safety;
D O I：
10.1016/j.ces.2007.03.016
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
A concept of the safety boundary diagram, elaborated in our previous studies for liquid-liquid heterogeneous reactions, has been developed here for liquid-phase homogeneous semibatch reactors. With the use of this boundary diagram, inherently safe-operating conditions can be easily determined without costly and time-consuming kinetic studies. A rapid procedure to estimate the dosing time and the cooling temperature appropriate for inherently safe operation of the reactor has been elaborated and proposed. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5074 / 5077
页数：4
相关论文
共 50 条
  • [41] Homogeneous distribution of sintering additives in liquid-phase sintered silicon carbide
    Swedish Ceramic Inst, Goeteborg, Sweden
    J Am Ceram Soc, 7 (1761-1768):
  • [42] SUPPORTED LIQUID-PHASE CATALYTIC MEMBRANE REACTOR SEPARATOR FOR HOMOGENEOUS CATALYSIS
    KIM, JS
    DATTA, R
    AICHE JOURNAL, 1991, 37 (11) : 1657 - 1667
  • [43] TRANSITION-METAL HOMOGENEOUS CATALYSIS FOR LIQUID-PHASE DEHYDROGENATION OF METHANOL
    ITAGAKI, H
    SAITO, Y
    SHINODA, S
    JOURNAL OF MOLECULAR CATALYSIS, 1987, 41 (1-2): : 209 - 220
  • [44] SURFACE-TENSION OF NUCLEUS OF LIQUID-PHASE IN HOMOGENEOUS VAPOR CONDENSATION
    VIZEL, YM
    MOSTINSKII, IL
    HIGH TEMPERATURE, 1975, 13 (04) : 687 - 690
  • [45] Homogeneous Liquid-Phase Oxidation of Ethylbenzene to Acetophenone in Continuous Flow Mode
    Gutmann, Bernhard
    Elsner, Petteri
    Roberge, Dominique
    Kappe, C. Oliver
    ACS CATALYSIS, 2013, 3 (12): : 2669 - 2676
  • [46] MECHANISM OF THE LIQUID-PHASE HOMOGENEOUS OXIDATION OF ALKYLAROMATIC HYDROCARBONS BY COBALT SALTS
    HANOTIER, J
    HANOTIERBRIDOUX, M
    JOURNAL OF MOLECULAR CATALYSIS, 1981, 12 (02): : 133 - 147
  • [47] Modeling of gas-liquid reactors. Isothermal semibatch and continuous stirred tank reactors
    Markos, J
    Pisu, M
    Morbidelli, M
    COMPUTERS & CHEMICAL ENGINEERING, 1998, 22 (4-5) : 627 - 640
  • [48] PREVENTION OF OXIDE FORMATION DURING LIQUID-PHASE EPITAXY OF SILICON
    WEBER, KJ
    BLAKERS, AW
    APPLIED PHYSICS LETTERS, 1995, 66 (10) : 1243 - 1245
  • [49] Safety Criteria for Solid-Liquid Heterogeneous Systems in Semibatch Reactors
    Ran, Zheng
    Ni, Lei
    Pan, Yong
    Chen, Yutong
    Wang, Jun
    Jiang, Juncheng
    Shu, Chi-Min
    ACS OMEGA, 2022, 7 (24): : 21207 - 21219
  • [50] Modeling of gas-liquid reactors. Isothermal semibatch and continuous stirred tank reactors
    CRS4-Centre for Advanced Studies, Research and Development in Sardinia, via Nazario Sauro, 10, I-09123 Cagliari, Italy
    不详
    不详
    Comput. Chem. Eng., 4-5 /5 (627-640):
12345