Runaway prevention in liquid-phase homogeneous semibatch reactors

被引：28
|
作者：
Molga, Eugeniusz J.
Lewak, Michal
Roel Westerterp, K.
机构：
[1] Warsaw Univ Technol, Dept Chem & Proc Engn, PL-00645 Warsaw, Poland
[2] Ramon Llull Univ, Inst Quim Sarria, Barcelona 08017, Spain
来源：
CHEMICAL ENGINEERING SCIENCE | 2007年 / 62卷 / 18-20期
关键词：
chemical reactors; heat transfer; homogeneous reactions; thermal runaway; reaction engineering; safety;
D O I：
10.1016/j.ces.2007.03.016
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
A concept of the safety boundary diagram, elaborated in our previous studies for liquid-liquid heterogeneous reactions, has been developed here for liquid-phase homogeneous semibatch reactors. With the use of this boundary diagram, inherently safe-operating conditions can be easily determined without costly and time-consuming kinetic studies. A rapid procedure to estimate the dosing time and the cooling temperature appropriate for inherently safe operation of the reactor has been elaborated and proposed. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5074 / 5077
页数：4
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