Bis(μ-3,5-di-2-pyridyl-1,2,4-triazolato-κ4N1,N5:N2,N3)bis[(methanol-κO)(thiocyanato-κN)iron(II)]

被引:1
|
作者
Jiang, Gang-Biao
Zeng, Xin-Nian
Fang, Yu-Sheng
Zeng, Ming-Hua
Ng, Seik Weng [1 ]
机构
[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
[2] Guangxi Normal Univ, Dept Chem, Guilin 541000, Guangxi, Peoples R China
关键词
D O I
10.1107/S1600536807039177
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title centrosymmetric dinuclear iron(II) compound, [Fe-2(C12H8N5)(2)(NCS)(2)(CH4O)(2)], the deprotonated 3,5-di-2-pyridyl-1,2,4-triazole ligand uses a pair of N-pyridyl/N-triazolyl atoms to chelate one metal atom and the other pair of N-pyridyl/N-triazolyl atoms to chelate the other metal atom. Each Fe atom is octahedrally coordinated by four N atoms surrounding the metal center in a square-planar environment. Above and below this plane are located the N atom of the thiocyanate anion and the O atom of the methanol molecule. Intermolecular O-H center dot center dot center dot N hydrogen bonding gives rise to a layer motif.
引用
收藏
页码:M2319 / U675
页数:9
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