Process Optimisation of In Situ H2 Generation From Ammonia Using Ni on Alumina Coated Cordierite Monoliths

被引：10

作者：

Plana, Carlos ^{[1
]}

Armenise, Sabino ^{[1
,2
]}

Monzon, Antonio ^{[2
]}

Garcia-Bordeje, Enrique ^{[1
]}

机构：

[1] Inst Carboquim CSIC, Zaragoza 50018, Spain

[2] Univ Zaragoza, Dept Chem & Environm Engn, Inst Nanosci Aragon, Zaragoza 50018, Spain

来源：

TOPICS IN CATALYSIS | 2011年 / 54卷 / 13-15期

关键词：

Ni catalyst; Monolith; Alumina support; Ammonia decomposition; H-2; generation; DISPERSED NI/AL2O3 CATALYSTS; COX-FREE HYDROGEN; NH3; DECOMPOSITION; PROMOTED RU; KINETICS; STORAGE;

D O I：

10.1007/s11244-011-9706-x

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A catalyst of Ni supported on alumina coated monolith has been prepared, characterized and tested in NH3 decomposition. The characterization of the catalyst by XPS and TPR showed that there is no formation of aluminates after catalyst use. It is studied the effect of the space velocity, by varying the feed flow rate and the catalyst's length. Some evidences are shown about the reaction inhibition by produced H-2 and about the reasons for the better performance of the monolith than packed bed catalyst.

引用

页码：914 / 921

页数：8

共 50 条

[41] Charge characteristics of silica particles using in situ sampling from H2/O2/TEOS diffusion flame
Jung, C.H.
Ahn, K.H.
Choi, M.
Lee, J.S.
Journal of Aerosol Science, 2000, 31 (SUPPL.1)
[42] SOLAR H2 PRODUCTION FROM A TWO-STEP WATER SPLITTING PROCESS WITH METAL (FE, NI) DOPED CERIA
Kaneko, H.
Naganuma, Y.
Taku, S.
Ouchi, K.
Hasegawa, N.
Tamaura, Y.
ES2008: PROCEEDINGS OF THE 2ND INTERNATIONAL CONFERENCE ON ENERGY SUSTAINABILITY, VOL 2, 2009, : 397 - 402
[43] Systematic optimization of H2 recovery from water splitting process using membranes and N2 diluent
Alsayegh, Sari
Johnson, J. R.
Ohs, Burkhard
Lohaus, Johannes
Wessling, Matthias
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (09) : 6000 - 6011
[44] Electrocatalytic generation of H2 from neutral water in acetonitrile using manganese polypyridyl complexes with ligand assistance
Rao, Gyandshwar Kumar
Jamshidi, Mohammad Parsa
Dawkins, Jeremy I. G.
Pell, Wendy
Korobkov, Ilia
Richeson, Darrin
DALTON TRANSACTIONS, 2017, 46 (20) : 6518 - 6522
[45] N, P self-mixing microporous carbon supported RuCo alloys for " on - off " control H2 generation from ammonia borane
Zhang, Jie
Zhang, Yaoyao
Zhu, Zhihui
Pu, Yan
Wang, Huali
Tang, Ning
Fan, Guangyin
Wang, Yi
JOURNAL OF ALLOYS AND COMPOUNDS, 2025, 1010
[46] N-doped mesoporous carbon embedded Co nanoparticles for highly efficient and stable H2 generation from hydrolysis of ammonia borane
Zhang, Fengwei
Ma, Chunlan
Zhang, Yu
Li, Huan
Fu, Dongying
Du, Xiaoqiang
Zhang, Xian-Ming
JOURNAL OF POWER SOURCES, 2018, 399 : 89 - 97
[47] N, P self-mixing microporous carbon supported RuCo alloys for on–off control H2 generation from ammonia borane
Wang, Yi (wangyi@sicnu.edu.cn), 1600, Elsevier Ltd (1010):
[48] Low temperature H2 production from ammonia using ruthenium-based catalysts: Synergetic effect of promoter and support
Hill, Alfred K.
Torrente-Murciano, Laura
APPLIED CATALYSIS B-ENVIRONMENTAL, 2015, 172 : 129 - 135
[49] Visible-light-induced unbalanced charge on NiCoP/TiO2 sensitized system for rapid H2 generation from hydrolysis of ammonia borane
Wang, Yutong
Shen, Guoqiang
Zhang, Yuxi
Pan, Lun
Zhang, Xiangwen
Zou, Ji-Jun
APPLIED CATALYSIS B-ENVIRONMENTAL, 2020, 260
[50] CFD modeling of two-stage H2 recovery process from ammonia purge stream by industrial hollow fiber membrane modules
Ardaneh, Morteza
Abolhasani, Mahdieh
Esmaeili, Majid
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (10) : 4851 - 4867

← 1 2 3 4 5 →