All-solid secondary polyaniline-zinc battery

被引：16
|
作者：
Sivaraman, P. [1 ]
Thakur, A. P. [1 ]
Kushwaha, R. K. [1 ]
Ratna, D. [1 ]
Samui, A. B. [1 ]
机构：
[1] Naval Mat Res Lab, Ambernath 421506, Maharashtra, India
来源：
JOURNAL OF APPLIED ELECTROCHEMISTRY | 2008年 / 38卷 / 02期
关键词：
battery; polyaniline; gel polymer electrolyte; zinc;
D O I：
10.1007/s10800-007-9422-1
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
A solid state battery based on polyaniline (PANI), Zinc (Zn) and a gel polymer electrolyte (GPE) is reported for the first time. Poly (ethylene oxide)-zinc sulphate-nanoclay-H2O based GPE was used as the separator. The GPEs with a varying composition of salt were evaluated for their electrochemical performance. The highest conductivity at ambient temperature for the GPEs was found to be 5.54 x 10(-4) S cm(-1). Cyclic voltammetry and impedance studies, with the Zn/GPE/Zn cell, showed reversibility with respect to Zn/Zn2+ couple. The battery showed a capacity of 43.9 Ah kg(-1) of PANI and a coulombic efficiency higher than 100%. However, a decrease in capacity was observed for the system during the cycling.
引用
收藏
页码：189 / 195
页数：7
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