First total synthesis of 11-tellura steroids

被引：11
|
作者：
Ibrahim-Ouali, Malika [1 ,2 ]
机构：
[1] CNRS, Inst Sci Mol Marseille, UMR 6263, F-13397 Marseille 20, France
[2] Univ Aix Marseille 3, Fac Sci & Tech St Jerome, F-13397 Marseille 20, France
来源：
TETRAHEDRON LETTERS | 2010年 / 51卷 / 28期
关键词：
1,8-Bis(trimethylsilyl)-2,6-octadiene; Tellura steroids; Intramolecular Diels-Alder reaction; Thermolysis; INTRAMOLECULAR CYCLOADDITION REACTIONS; PALLADIUM-CATALYZED OXIDATION; 11-OXA STEROIDS; ORGANIC-SYNTHESIS; CONVENIENT SYNTHESIS; CHANDONIUM IODIDE; 11-AZA STEROIDS; PRODUCTS; KETONES; ORGANOSELENIUM;
D O I：
10.1016/j.tetlet.2010.05.008
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The first total synthesis of 11-tellura steroids was achieved via an intramolecular Diels-Alder cycloaddition of o-quinodimethanes as the key step. (C) 2010 Elsevier Ltd. All rights reserved.
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页码：3610 / 3612
页数：3
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