A new diamantane functionalized tris(aryloxide) ligand system for small molecule activation chemistry at reactive uranium complexes

被引：24

作者：

Lam, Oanh P. ^{[1
,2
]}

Heinemann, Frank W. ^{[1
]}

Meyer, Karsten ^{[1
]}

机构：

[1] Univ Erlangen Nurnberg, Dept Chem & Pharm, D-91058 Erlangen, Germany

[2] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA

来源：

COMPTES RENDUS CHIMIE | 2010年 / 13卷 / 6-7期

关键词：

Uranium; Tripodal ligands; Chelates; Macrocyclic; Diamantane; COORDINATION;

D O I：

10.1016/j.crci.2010.03.004

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The diamantane functional ized triazacyclononane ligand ((Dia)ArOH)(3)tacn (L(3)) has been synthesized and the reactivity of its U(III) metallated product [(((Dia)ArO)(3)tacn)U] (1) has been explored. Complex 1 promotes dichloromethane and azidotrimethylsilane activation to generate U(IV) complex [(((Dia)ArO)(3)tacn)U(Cl] (2) and U(V) complex 1(((Dia)ArO)(3)tacn)U(NTMS)] (3), respectively. Spectroscopic investigations of complexes 1, 2, and 3 will be discussed, along with molecular structures where possible (C) 2010 Published by Elsevier Masson SAS on behalf of Academic des sciences

引用

页码：803 / 811

页数：9

共 35 条

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