Two- and three-dimensional frameworks constructed from bicapped Keggin clusters

被引：83
|
作者：
Duan, LM
Pan, CL
Xu, JQ [1 ]
Cui, XB
Xie, FT
Wang, TG
机构：
[1] Jilin Univ, Coll Chem, Changchun 130023, Peoples R China
[2] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China
[3] Inner Mongolia Univ Nationalities, Coll Chem, Tongliao 028000, Peoples R China
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 14期
关键词：
polyoxometalates; hydrothermal synthesis; cluster compounds; crystal structure;
D O I：
10.1002/ejic.200300070
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The novel two- and three-dimensional solid materials [Cu(en)(2)(H2O)]{(PMo8VV6O42)-V-VI-V-IV[Cu-0.5(en)](3)}.5.5H(2)O and H-3{(VMo8V6O42)-Mo-V-V-VI-O-IV[Cu(en)(2)](4)}[MoO4](2).14H(2)O (en = ethylenediamine) have been hydrothermally assembled and structurally characterized. Both networks are based on mixed Mo/V bicapped Keggin clusters interconnected through the transition metal complex moieties. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.
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页码：2578 / 2581
页数：4
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