Crystal structure of the complex of brominated diphenyl ethers from the marine sponge Dysidea fragilis

被引:0
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作者
Ilin, SG [1 ]
Utkina, NK [1 ]
Veselova, MV [1 ]
Struchkov, YT [1 ]
机构
[1] RUSSIAN ACAD SCI,AN NESMEYANOV ORGANOELEMENT CPDS INST,MOSCOW 117813,RUSSIA
关键词
brominated diphenyl ethers; marine sponges; crystal and molecular structure;
D O I
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The spatial structures of 2-(2',4'-dibromophenoxy)-3,4,5-tribromophenol (1) and 2-(2'-hydroxy-4',6'-dibromophenoxy)-4,6-dibromoanisole (2) in crystals of the complex formed through two intermolecular O--H...O bonds were determined. The conformations of both molecules were found to be stabilized by intramolecular hydrogen bonds. The external hydrophobic surface of the complex of two molecules was shown to be occupied by nine bromine atoms.
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页码:717 / 719
页数:3
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