N,N-Bis(diphenylphosphanyl)cyclopentanamine

被引:4
|
作者
Engelbrecht, Ilana [1 ]
Visser, Hendrik G. [1 ]
Roodt, Andreas [1 ]
机构
[1] Univ Orange Free State, Dept Chem, ZA-9300 Bloemfontein, South Africa
基金
新加坡国家研究基金会;
关键词
DIPHOSPHINOAMINES;
D O I
10.1107/S1600536810048907
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The coordination around the N atom in the title compound, C29H29NP2, shows an almost planar geometry, defined by the attached P and C atoms, in order to accomodate the steric bulk of the phenyl rings. The distortion of the trigonal-pyramidal geometry of the N atom is illustrated by the bond angles ranging between 115.22 (12) and 121.76 (9)degrees. The P atoms present a pyramidal environment with bond angles ranging from 100.62 (9) to 104.71 (8)degrees. One of the C atoms in the cyclopentyl ring displays a 0.822 (4):0.178 (4) positional disorder. Within the crystal structure, intramolecular C-H center dot center dot center dot P hydrogen bonds together with inter-and intramolecular C-H center dot center dot center dot pi interactions link the molecules into a supra-molecular two-dimensional network.
引用
收藏
页码:O3322 / U2029
页数:13
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