Copper-catalyzed C-P cross-coupling of arylmethyl quaternary ammonium salts via C-N bond cleavage

被引：9

作者：

Li, Nutao ^{[1
]}

Chen, Feng ^{[1
]}

Wang, Guanghui ^{[1
]}

Zeng, Qingle ^{[1
]}

机构：

[1] Chengdu Univ Technol, Coll Mat Chem & Chem Engn, State Key Lab Geohazard Prevent & Geoenvironm Pro, Chengdu 610059, Sichuan, Peoples R China

来源：

MONATSHEFTE FUR CHEMIE | 2020年 / 151卷 / 01期

关键词：

Copper; Cross-coupling; C-N cleavage; Arylmethyl quaternary ammonium salts; Dialkylphosphine oxides; ARYLBORONIC ACIDS; ANTAGONIST; FOSTEDIL; OXIDES;

D O I：

10.1007/s00706-019-02535-y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A ligand-free copper-catalyzed C-P cross-coupling reaction of arylmethyl quaternary ammonium salts and diarylphosphine oxides in air is developed. Arylmethyl quaternary ammonium salts with various functional groups and a variety of dialkyl- and diarylphosphine oxides afford C-P cross-coupling products with good yields. This protocol requires no inert atmosphere, no ligand, and simple operation steps.

引用

页码：99 / 106

页数：8

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