Effect of equivalence ratio and temperature on soot formation in partially premixed counterflow flames

Soot formation is quantified in detail (volume fraction, particle size, number concentration, and light emissivity dispersion exponent) in a series of partially premixed counterflow flames of ethylene at equivalence ratios, Phi, equal to 6.5, 5.0, and 4.0, and with maximum temperature spanning approximately 200?K. The focus is to investigate the effect of peak temperature and equivalence ratio on soot formation while maintaining constant global strain and stoichiometric mixture fraction. Oxygen is progressively displaced from the oxidizer to the fuel stream of a diffusion flame to stabilize partially premixed flames of decreasing Phi, showing a double-flame structure consisting of a rich premixed flame component stabilized on the fuel side of the stagnation plane and a diffusion flame component stabilized on the oxidizer side. Soot is detected in the region sandwiched between the two flame components, is formed in both of them, and is convected away radially at the Particle Stagnation Plane (PSP). At fixed Phi, raising the peak temperature invariably raises the soot volume fraction throughout the probed region. Vice versa, at fixed peak temperature, lowering the equivalence ratio causes the premixed flame component to shift away from the diffusion flame component, with the consequent broadening of the soot forming region and an increase in both soot volume fraction as well as soot particle sizes through an enhancement of surface growth. Detailed probing of the region in the vicinity of the PSP offers evidence of soot oxidation from molecular oxygen. Furthermore, when the maximum temperature is sufficiently low, the net soot production rate turns negative because surface oxidation overwhelms surface growth. Comparing the soot number production rate inferred from experiments to the dimerization rate of benzene (C6H6), naphthalene (C10H8), and pyrene (C16H10) reveals that only the smallest aromatics are present in flames at sufficiently large concentrations to account for soot nucleation. This observation applies to both the diffusion flame and the premixed flame components and confirms previous findings in strictly diffusion flames. (C) 2022 The Combustion Institute. Published by Elsevier Inc. All rights reserved.