One-dimensional helical Cu(II) coordination polymer: Synthesis, structures, and properties

被引：4

作者：

Zhao, Xiao-Qing ^{[1
,2
]}

Wang, Yi-Yan ^{[1
]}

Xiang, Shuo ^{[1
]}

Lv, Chuan ^{[1
]}

Liu, Ya-Jun ^{[1
]}

Xu, Fu-Sen ^{[1
]}

Bao, Dong-Xu ^{[1
]}

Wang, Jin ^{[1
]}

机构：

[1] Sichuan Agr Univ, Coll Sci, Yaan 625014, Peoples R China

[2] Nankai Univ, Minist Educ, Key Lab Adv Energy Mat Chem, Tianjin 300071, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2017年 / 85卷

关键词：

Cu(II) coordination polymer; Helical; Luminescence; Magnetic susceptibility; Electrocatalyst; METAL-ORGANIC FRAMEWORKS; ACID-BASE-EQUILIBRIUM; NETWORK STRUCTURES; WATER SOLUBILITY; COMPLEXES; CATALYSTS; CRYSTAL; TRANSFORMATION; HYDROGENATION; BIPYRIDINE;

D O I：

10.1016/j.inoche.2017.05.030

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

One new Cu(II) coordination polymer (1) based on 6,6'-dihydroxy-2,2'-bipyridine (H(2)dhbp) was successfully prepared, with the formula of [Cu(mu(2)-OH)(Hdhbp)](n), (1). Single-crystal X-ray analysis shows that compound 1 crystallizes in orthorhombic chiral space group P2(1)2(1)2(1) and exhibits a left-handed (L) helical [Cu(mu(2)-OH)](n)-chain. Luminescence of 1 exhibits a broad emission around 440 nm, attributing to the metal to ligand charge transfer (MLCT). Magnetic susceptibility shows antiferromagnetic coupling within compound 1. Cyclic voltammetry (CV) experiments indicate a potential water oxidation electrocatalyst. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：49 / 51

页数：3

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