Synthesis, Crystal Structure, and Characterization of a Novel One-Dimensional Helical Chain Cobalt(II) Coordination Polymer

被引：2

作者：

Zhang, Wei-Guo ^{[2
]}

Dong, Gui-Ying ^{[1
]}

Liu, Tong-Fei ^{[1
]}

Cui, Guang-Hua ^{[1
]}

机构：

[1] Hebei United Univ, Coll Chem Engn, Tangshan 063009, Hebei, Peoples R China

[2] Hebei Normal Univ Sci & Technol, Coll Phys & Chem, Qinhuangdao, Hebei, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2012年 / 42卷 / 04期

关键词：

4-N-(2 '-pyridylimine)benzoic acid; Co(II) complexes; crystal structure; 1D helical chain; 3D framework; ANTI CARBOXYLATE BRIDGES; COPPER(II) COMPLEX; MAGNETIC-PROPERTIES; LIGAND; FRAMEWORK; RHENIUM; DESIGN; ACID;

D O I：

10.1080/15533174.2011.613081

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel one-dimensional (1D) helical chain polymer, {[CoL2(H2O)](H3O)(ClO4)}(n) (1) (HL = 4-N-(2'-pyridylimine)benzoic acid), was synthesized by reaction of Co(II) perchlorate with L anion in ethanol solution, and characterized by element analyses, infrared spectroscopy, and X-ray single-crystal diffraction. In this structure, the Co2+ ion is in a distorted octahedral geometry, an infinite 1D helical chain was constructed by L ligand through bidentate-monodentate bridging modes and are further assembled into three-dimensional supramolecular networks through complicated O-H center dot center dot center dot Ohydrogen bonding interactions.

引用

页码：475 / 479

页数：5

共 50 条

[1] Hydrothermal Synthesis and Crystal Structure of a New Co(II) Coordination Polymer With One-Dimensional Helical Chains
Feng, Xiuling
Chen, Wanping
Xiang, Bolin
[J]. SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2016, 46 (09) : 1306 - 1309
[2] Hydrothermal Synthesis and Crystal Structure of a One-dimensional Cobalt (II) Coordination Polymer with Two Organic Ligands
Huang-Fu, You-Jing
Pan, Hui
Hao, Xi-Cai
Bai, Yan
Dang, Dong-Bin
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2014, 69 (06): : 699 - 703
[3] Synthesis and Crystal Structure of a Coordination Polymer [Zn（p-pdoa）(bbp)]_n with a One-dimensional Helical Chain
杨燕
曾明华
张来军
梁宏
[J]. 结构化学., 2008, (06) - 752
[4] Synthesis and crystal structure of a coordination polymer [Zn(p-pdoa)(bbp)]n with a one-dimensional helical chain
Yang Yan
Zeng Ming-Hua
Zhang Lai-Jun
Liang Hong
[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2008, 27 (06) : 749 - 752
[5] Synthesis and Crystal Structure of a Coordination Polymer [Zn（p-pdoa）(bbp)]n with a One-dimensional Helical Chain
杨燕
曾明华
张来军
梁宏
[J]. Chinese Journal of Structural Chemistry, 2008, (06) : 749 - 752
[6] Synthesis, structure and magnetic property of a one-dimensional Co(II)-formate helical coordination polymer
Yuan, Pei-Lin
Li, Pei-Zhou
Sun, Qing-Fu
Liu, Li-Xia
Gao, Kun
Liu, Wei-Sheng
Lu, Xiao-Ming
Yu, Shu-Yan
[J]. JOURNAL OF MOLECULAR STRUCTURE, 2008, 890 (1-3) : 112 - 115
[7] Synthesis, Structure, and Characterization of a Novel One-Dimensional Mixed-Ligand Coordination Polymer of Copper(II)
He, Cui-Hong
Liu, Tong-Fei
Jiao, Cui-Huan
Cui, Guang-Hua
[J]. SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2011, 41 (10) : 1305 - 1309
[8] Synthesis, crystal structure and luminescent property of a novel H2O-bridged cobalt(II) polymer with one-dimensional chain structure
Yang, En-Cui
Dai, Pei-Xia
Wang, Xiu-Guang
Zhao, Xiao-Jun
[J]. TRANSITION METAL CHEMISTRY, 2007, 32 (02) : 228 - 232
[9] Synthesis, crystal structure and luminescent property of a novel H2O-bridged cobalt(II) polymer with one-dimensional chain structure
En-Cui Yang
Pei-Xia Dai
Xiu-Guang Wang
Xiao-Jun Zhao
[J]. Transition Metal Chemistry, 2007, 32 : 228 - 232
[10] Hydrothermal synthesis, crystal structure and property of a one-dimensional Cu(II) coordination polymer
Sun, Li Ping
Niu, Shu Yun
Jin, Jing
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 230 : U2067 - U2067

← 1 2 3 4 5 →