Dinuclear complex of gold(III) with 1,3-diaminopropane (HL), [Au2(HL)(L)2](ClO4)3(OH): Synthesis and crystal and molecular structures

被引：2

作者：

Afanas'eva, V. A. ^{[1
]}

Glinskaya, L. A. ^{[1
]}

Klevtsova, R. F. ^{[1
]}

Mironov, I. V. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, Novosibirsk 630090, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2010年 / 36卷 / 09期

关键词：

GOLD NITROGEN-HETEROCYCLES; TEMPLATE SYNTHESIS; ALKOXO COMPLEXES; TRICHLORIDE; LIGANDS; HYDROXO; OXO;

D O I：

10.1134/S1070328410090101

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dinuclear gold(III) complex, [Au-2(HL)(L)(2)](ClO4)(3)(OH) (I) (HL = 1,3-diaminopropane), with two amide bridges has been synthesized for the first time. According to the X-ray diffraction data, the crystal structure of complex I consists of the complex cations [Au-2(HL)(L)(2)](4+) and anions ClO (4) (-) and OH-. The coordination sites AuN4 are insignificantly distorted squares. In the four-membered ring Au2N2, the gold atoms are bound by the bridging nitrogen atoms of the deprotonated primary amine.

引用

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页码：697 / 703

页数：7

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