Dinuclear complex of gold(III) with 1,3-diaminopropane (HL), [Au2(HL)(L)2](ClO4)3(OH): Synthesis and crystal and molecular structures

被引：2

作者：

Afanas'eva, V. A. ^{[1
]}

Glinskaya, L. A. ^{[1
]}

Klevtsova, R. F. ^{[1
]}

Mironov, I. V. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, Novosibirsk 630090, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2010年 / 36卷 / 09期

关键词：

GOLD NITROGEN-HETEROCYCLES; TEMPLATE SYNTHESIS; ALKOXO COMPLEXES; TRICHLORIDE; LIGANDS; HYDROXO; OXO;

D O I：

10.1134/S1070328410090101

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dinuclear gold(III) complex, [Au-2(HL)(L)(2)](ClO4)(3)(OH) (I) (HL = 1,3-diaminopropane), with two amide bridges has been synthesized for the first time. According to the X-ray diffraction data, the crystal structure of complex I consists of the complex cations [Au-2(HL)(L)(2)](4+) and anions ClO (4) (-) and OH-. The coordination sites AuN4 are insignificantly distorted squares. In the four-membered ring Au2N2, the gold atoms are bound by the bridging nitrogen atoms of the deprotonated primary amine.

引用

下载

页码：697 / 703

页数：7

共 50 条

[1] Dinuclear complex of gold(III) with 1,3-diaminopropane (HL), [Au2(HL)(L)2](ClO4)3(OH): Synthesis and crystal and molecular structures
V. A. Afanas’eva
L. A. Glinskaya
R. F. Klevtsova
I. V. Mironov
Russian Journal of Coordination Chemistry, 2010, 36 : 697 - 703
[2] THE CRYSTAL-STRUCTURE OF [PT(1,3-DIAMINOPROPANE)2][PT(1,3-DIAMINOPROPANE)2CL2](CLO4)4 - FURTHER REMARKS ON ORDER AND DISORDER IN WOLFFRAMS RED SALT ANALOGS
CANNAS, M
MARONGIU, G
NAVARRA, G
GAZZETTA CHIMICA ITALIANA, 1989, 119 (06): : 349 - 352
[3] THE CRYSTAL-STRUCTURE AND DEPROTONATION OF A COBALT(III) COMPLEX [CO(HL)L](CLO4)2, WHERE HL=2-(3-AMINO-PROPYL)IMINO-3-BUTANONE OXIME
KORVENRANTA, J
SAARINEN, H
RAIKAS, T
NASAKKALA, E
FINNISH CHEMICAL LETTERS, 1981, (3-4): : 29 - 34
[4] THERMOAQUATION AND PHOTOAQUATION OF TRANS-[CR(1,3-DIAMINOPROPANE)2(CN)2]CLO4 - QUENCHING OF PHOTOCHEMISTRY BY PHOTOPRODUCTS
KIRK, AD
FERNANDO, SRL
INORGANIC CHEMISTRY, 1992, 31 (04) : 656 - 661
[5] Spectroscopic study on a photoluminescent host-guest complex [Au2 (μ-PNP)3] (ClO4)2
Li, D
Che, CM
ACTA CHIMICA SINICA, 2000, 58 (11) : 1429 - 1433
[6] Synthesis, Characterization, Crystal Structures, and Antimicrobial Activities of N, N′-Bis(3-Bromo-2-Hydroxybenzylidene)-1,3-Diaminopropane and Its Dinuclear Copper(II) Complex
Wang, Na
Qiu, Xiao-Yang
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2015, 45 (02) : 185 - 190
[7] Synthesis and crystal and molecular structure of β-chlorinated acyclic complex of gold(III) [Au(C9H18N4Cl)](ClO4)2
Afanasieva, V. A.
Glinskaya, L. A.
Klevtsova, R. F.
Mironov, I. V.
Sheludyakova, L. A.
JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 46 (05) : 869 - 875
[8] Synthesis and crystal and molecular structure of β-chlorinated acyclic complex of gold(III) [Au(C9H18N4Cl)](ClO4)2
V. A. Afanasieva
L. A. Glinskaya
R. F. Klevtsova
I. V. Mironov
L. A. Sheludyakova
Journal of Structural Chemistry, 2005, 46 : 869 - 875
[9] A DINUCLEAR COPPER(II) COMPLEX [CU2L2](CLO4)2 DERIVED FROM 2,6-BIS(AMINOMETHYL)-4-METHYLPHENOL (HL)
MUKHERJEE, M
MUKHERJEE, AK
DUTTA, SK
NANDA, KK
HELLIWELL, M
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1994, 50 : 542 - 544
[10] THE 1ST FERROMAGNETIC TETRANUCLEAR NICKEL(II) COMPLEX WITH A MU-AZIDO BRIDGE - STRUCTURE AND MAGNETIC-PROPERTIES OF [NI4(MU-N3)4(2-OXO-1,3-DIAMINOPROPANE)2(2-HYDROXO-1,3-DIAMINOPROPANE)2](CLO4)2
RIBAS, J
MONFORT, M
COSTA, R
SOLANS, X
INORGANIC CHEMISTRY, 1993, 32 (05) : 695 - 699

← 1 2 3 4 5 →