Preparation and crystal structural characterization of Cu(II) complex with piperidine-4-carboxylic acid

被引：2
|
作者：
Yang, JX
Zhang, Z
Tian, YP [1 ]
Wu, JY
Liu, QL
Usman, A
Chantrapromma, S
Fun, HK
机构：
[1] Anhui Univ, Dept Chem, Hefei 230039, Peoples R China
[2] USTC, Dept Chem, Anhua 230026, Peoples R China
[3] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, George Town 11800, Malaysia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2005年 / 31卷 / 04期
关键词：
D O I：
10.1007/s11173-005-0089-z
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Copper(II) complex with piperidine-4-carboxylic acid (HPipe-4), Cu(HPipe-4)(4)(ClO4)(2) (I) was prepared and characterized by IR, X-ray diffraction, and thermal analysis. The crystal is orthorhombic with space group Ccca, Z = 8, a = 17.415(3) angstrom, b = 17.399(2) angstrom, c = 21.426(3) angstrom. The copper atom has a square surrounding and is coordinated by four carboxylato oxygen atoms in monodentate coordination mode. Full-matrix least-squares refinements gave a final R value of 0.0723 for 22169 reflections. The complex consists of two perpendicularly arranged molecules differing slightly in conformations and shows a three-dimensional polymeric structure formed by hydrogen bonds.
引用
收藏
页码：282 / 285
页数：4
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