Preparation and crystal structural characterization of Cu(II) complex with piperidine-4-carboxylic acid

被引：2
|
作者：
Yang, JX
Zhang, Z
Tian, YP [1 ]
Wu, JY
Liu, QL
Usman, A
Chantrapromma, S
Fun, HK
机构：
[1] Anhui Univ, Dept Chem, Hefei 230039, Peoples R China
[2] USTC, Dept Chem, Anhua 230026, Peoples R China
[3] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, George Town 11800, Malaysia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2005年 / 31卷 / 04期
关键词：
D O I：
10.1007/s11173-005-0089-z
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Copper(II) complex with piperidine-4-carboxylic acid (HPipe-4), Cu(HPipe-4)(4)(ClO4)(2) (I) was prepared and characterized by IR, X-ray diffraction, and thermal analysis. The crystal is orthorhombic with space group Ccca, Z = 8, a = 17.415(3) angstrom, b = 17.399(2) angstrom, c = 21.426(3) angstrom. The copper atom has a square surrounding and is coordinated by four carboxylato oxygen atoms in monodentate coordination mode. Full-matrix least-squares refinements gave a final R value of 0.0723 for 22169 reflections. The complex consists of two perpendicularly arranged molecules differing slightly in conformations and shows a three-dimensional polymeric structure formed by hydrogen bonds.
引用
收藏
页码：282 / 285
页数：4
相关论文
共 50 条
  • [1] Preparation and crystal structural characterization of Cu(II) complex with piperidine-4-carboxylic acid
    J. X. Yang
    Z. Zhang
    Y. P. Tian
    J. Y. Wu
    Q. L. Liu
    A. Usman
    S. Chantrapromma
    H. K. Fun
    Russian Journal of Coordination Chemistry, 2005, 31 : 282 - 285
  • [2] Preparation and crystal structural characterization of Cu(II) complex with piperidine-4-carboxylic acid
    Yang, J.X.
    Zhang, Z.
    Tian, Y.P.
    Wu, J.Y.
    Liu, Q.L.
    Usman, A.
    Chantrapromma, S.
    Fun, H.K.
    Koordinatsionnaya Khimiya, 2005, 31 (04): : 302 - 305
  • [3] The preparation of pyridine-4-carboxylic acid and of piperidine-4-carboxylic acid by catalytic reduction of 2,6-dichloropyridine-4-carboxylic acid
    Wibaut, JP
    RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS, 1944, 63 : 141 - 146
  • [4] Molecular structure, hydrogen bonding and spectroscopic properties of the complex of piperidine-4-carboxylic acid with chloroacetic acid
    Komasa, A.
    Katrusiak, A.
    Szafran, M.
    Barczynski, P.
    Dega-Szafran, Z.
    JOURNAL OF MOLECULAR STRUCTURE, 2008, 889 (1-3) : 112 - 118
  • [5] 1-(tert-Butoxycarbonyl)piperidine-4-carboxylic acid
    Fun, Hoong-Kun
    Arshad, Suhana
    Dinesh
    Vivek, S.
    Nagaraja, G. K.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O2215 - U1566
  • [6] Spectroscopic studies of the 1:1 complex of piperidine-4-carboxylic acid (isonipecotic acid) with 2,6-dichloro-4-nitrophenol
    Aniola, Michalina
    Dega-Szafran, Zofia
    Katrusiak, Andrzej
    Komasa, Anna
    Szafran, Miroslaw
    VIBRATIONAL SPECTROSCOPY, 2016, 85 : 35 - 42
  • [7] Synthesis and characterization of Piperidine-4-carboxylic acid functionalized Fe3O4 nanoparticles as a magnetic catalyst for Knoevenagel reaction
    Karaoglu, E.
    Baykal, A.
    Senel, M.
    Sozeri, H.
    Toprak, M. S.
    MATERIALS RESEARCH BULLETIN, 2012, 47 (09) : 2480 - 2486
  • [8] Synthesis and conductivity studies of piperidine-4-carboxylic acid functionalized Fe3O4 nanoparticles
    Erdemi, H.
    Baykal, A.
    Karaoglu, E.
    Toprak, M. S.
    MATERIALS RESEARCH BULLETIN, 2012, 47 (09) : 2193 - 2199
  • [9] INFLUENCE OF PIPERIDINE-4-CARBOXYLIC ACID ON THE ELECTROLYTIC STAINING OF ANODIZED ALUMINUM FROM NICKEL SULFATE-SOLUTIONS
    TSANGARAKIKAPLANOGLOU, I
    KARAGIANNI, B
    METALL, 1994, 48 (09): : 682 - 685
  • [10] Further studies of the addiction liability of demerol ( 1Methyl 4 phenyl piperidine-4-carboxylic acid ethyl ester hydrochloride)
    Himmelsbach, CK
    JOURNAL OF PHARMACOLOGY AND EXPERIMENTAL THERAPEUTICS, 1943, 79 (01): : 5 - 9
12345