Poly[[diaquabis(μ3-maleato-κ4O1:O1′,O4: O4′) dicopper(II)] trihydrate]

被引：1
|
作者：
Farnum, Gregory A. [1 ]
LaDuca, Robert L. [1 ]
机构：
[1] Michigan State Univ, Lyman Briggs Coll, Dept Chem, E Lansing, MI 48825 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词：
D O I：
10.1107/S1600536808023131
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, {[Cu(2)(C(4)H(2)O(4))(2)(H(2)O)(2)]center dot 3H(2)O}(n), Cu(II) ions with square-pyramidal coordination are bridged by exotridentate maleate dianions into [Cu(2)(maleate)(2)(H(2)O)(2)](n) layers coincident with the bc crystal plane. The interlamellar regions contain hydrogen-bonded cyclic water hexamers which facilitate layer stacking into a pseudo-three-dimensional crystal structure. The water hexamers themselves are formed by the operation of crystallographic inversion centers on sets of three crystallographically distinct water molecules of hydration.
引用
收藏
页码：M1074 / M1074
页数：1
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