Bis(1,4-diazacycloheptane-N,N′)nickel(II) diperchlorate

被引：7
|
作者：
Guo, YM [1 ]
Du, M [1 ]
Bu, XH [1 ]
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2001年 / 57卷
关键词：
D O I：
10.1107/S1600536801008030
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Ni(C5H12N2)(2)](ClO4)(2), consists of discrete [Ni(C5H12N2)(2)](2+) cations and perchlorate anions. The Ni II atom is at the center of symmetry and is coordinated in a square-planar manner by the nitrogen donors of a pair of mesocyclic 1,4-diazacycloheptane (DACH) ligands. Both DACH rings adopt boat conformations in the trans form. The perchlorate O atoms are hydrogen bonded with the nitrogen donors of the DACH rings to form a macrocycle-like system.
引用
收藏
页码：m280 / m282
页数：3
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