The synthesis of 3-acetyl-2-(4,4-dimethyl-2,6-dioxocyclohexyl)-1-phenylpentanedione-1,4 and its reactions with N-nucleophiles

被引:0
|
作者
Andin, AN [1 ]
Kaminskii, VA [1 ]
Dubovitskii, SV [1 ]
机构
[1] Far Eastern State Univ, Vladivostok 690950, Russia
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中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The respective adduct 3 has been prepared by condensation of dimedone 1 with 1,1-diacetyl-2-benzoylethylene 2. Its reactions with primary amines give the pyrroles 5ab, reaction with ammonium acetate gives the derivative of pyrrolo[3,4-c] quinoline 4. The derivative of pyridazine 6 has been prepared by reaction with hydrazine hydrate. The enamine of dimedone 7 reacts with 1,1-diacetyl-2-benzoylethylene 2 to give hexahydroquinoline 8.
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页码:155 / 158
页数:4
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