When "Metal atom clusters" meet ZnO nanocrystals:: A ((n-C4H9)4N)2Mo6Br14@ZnO hybrid

被引：52
|
作者：
Grasset, Fabien [1 ,2 ]
Molard, Yann [1 ]
Cordier, Stephane [1 ]
Dorson, Frederick [1 ]
Mortier, Michel [3 ]
Perrin, Christiane [1 ]
Guilloux-Viry, Maryline [1 ]
Sasaki, Toshio [2 ]
Haneda, Hajime
机构：
[1] Univ Rennes 1, CNRS UR1, UMR 6226, F-35042 Rennes, France
[2] Natl Inst Mat Sci, Int Ctr Young Scientists, Tsukuba, Ibaraki 3050044, Japan
[3] CNRS, Ecole Natl Super Chim Paris, UMR 7574, F-75005 Paris, France
来源：
ADVANCED MATERIALS | 2008年 / 20卷 / 09期
关键词：
D O I：
10.1002/adma.200701845
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Preparation and characterization of a luminescent hybrid nanocomposite, ((n-C4H9)(4)N)(2)Mo6Br14@ZnO, is achieved by using a straightforward fabrication process. The hybrid nanocomposite can be applied both under organosol and solid-state conditions. PL experiments show that the intrinsic photophysical properties of the cluster anion [Mo6Br14](2-) are not affected by its inclusion in the ZnO organosol. The obtained nanocomposite can be applied as a versatile luminescent nanomaterial with emissions ranging from 430 to 850 nm.
引用
收藏
页码：1710 / +
页数：7
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