Rh(III)-Catalyzed Oxidative Olefination of N-(1-Naphthyl)sulfonamides Using Activated and Unactivated Alkenes

被引：96
|
作者：
Li, Xuting [1 ,2 ]
Gong, Xue [1 ]
Zhao, Miao [1 ]
Song, Guoyong [1 ]
Deng, Jian [2 ]
Li, Xingwei [1 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
[2] Univ S China, Sch Chem & Chem Engn, Hengyang 421001, Peoples R China
来源：
ORGANIC LETTERS | 2011年 / 13卷 / 21期
关键词：
CATALYZED ORTHO-OLEFINATION; H BOND-CLEAVAGE; ARYL IODIDES; ALKYNES; DERIVATIVES; ARENES; ACIDS; N; N-DIMETHYLFORMAMIDE; FUNCTIONALIZATION; ALKYLATION;
D O I：
10.1021/ol2023856
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Rhodium(III)-catalyzed oxidative olefination of N-(1-naphthyl)sulfonamides has been achieved at the peri position. Three categories of olefins have been successfully applied. Activated olefins reacted to afford five-membered azacycles as a result of oxidative olefination-hydroamination. Unactivated olefins reacted to give the olefination product. 2-fold oxidative C-C and C-N coupling was achieved for allylbenzenes.
引用
收藏
页码：5808 / 5811
页数：4
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