Luminescence properties of the TRIMEB inclusion compound of a europium tris-β-diketonate

被引:5
|
作者
Braga, S. S. [1 ]
Coelho, A. C. [1 ]
Goncalves, I. S. [1 ]
Santos, G. [2 ]
Fonseca, F. J. [2 ]
Andrade, A. M. [2 ]
Peres, M. [3 ]
Simoes, W. [3 ]
Monteiro, T. [3 ]
Pereira, L. [3 ]
机构
[1] Univ Aveiro, Dept Quim & CICECO, P-3810193 Aveiro, Portugal
[2] Univ Sao Paulo, Escola Politecnica, Dept Engn Sistemas Elet, Lab Microelet, BR-05508900 Sao Paulo, Brazil
[3] Univ Aveiro, Dept Fis 13N, P-3810193 Aveiro, Portugal
关键词
sensors; optical spectroscopy;
D O I
10.1016/j.jnoncrysol.2007.09.053
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The adduct TRIMEB:Eu(BTA)(3)center dot 2H(2)O was prepared and primarily characterized by photoluminescence (PL), and compared with free Eu(BTA)(3)center dot 2H(2)O. Both spectra show the Eu3+ ion emission, with subtle differences between lines for the free and encapsulated complex. The temperature dependence and chemical stability were studied, taking into account (in the latter case) the PL changes with time. The use of this new material as the emissive layer in OLEDs was tested by its successful incorporation into a device, using a conductive polymer as host. The use of the TRIMEB adduct increased the stability of the device (as compared with the free Eu complex). (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:2736 / 2739
页数:4
相关论文
共 50 条
  • [21] Electronic structure and optical properties of Eu(III) tris-β-diketonate adducts with 1,10-phenanthroline
    Shurygin, A. V.
    Korochentsev, V. V.
    Cherednichenko, A. I.
    Mirochnik, A. G.
    Kalinovskaya, I. V.
    Vovna, V. I.
    JOURNAL OF MOLECULAR STRUCTURE, 2018, 1155 : 133 - 142
  • [22] Water enhances quantum yield and lifetime of luminescence of europium(III) tris-β-diketonates in concentrated toluene and acetonitrile solutions
    Voloshin, AI
    Shavaleev, NM
    Kazakov, VP
    JOURNAL OF LUMINESCENCE, 2001, 93 (03) : 191 - 197
  • [23] CORRELATION IN PARAMAGNETIC SHIFTS USING TRIS-(DIPIVALOMETHANATO)EUROPIUM(III)
    DOERFFEL, K
    EHRIG, R
    HAUTHAL, HG
    ZIMMERMA.G
    KASPER, H
    ZEITSCHRIFT FUR CHEMIE, 1972, 12 (02): : 74 - &
  • [24] Synthesis and Spectral Properties of Novel Fluorescent Poly(oxyethylene Phosphate) Tris(β-diketonate) Europium (III) Complexes
    Stanimirov, S.
    Vasilev, A.
    Haupt, E.
    Petkov, I.
    Deligeorgiev, T.
    JOURNAL OF FLUORESCENCE, 2009, 19 (01) : 85 - 95
  • [25] Synthesis and Spectral Properties of Novel Fluorescent Poly(oxyethylene Phosphate) Tris(β-diketonate) Europium (III) Complexes
    S. Stanimirov
    A. Vasilev
    E. Haupt
    I. Petkov
    T. Deligeorgiev
    Journal of Fluorescence, 2009, 19 : 85 - 95
  • [26] Influence of Lewis Bases on the Mesogenic and Luminescent Properties of Homogeneous Films of Europium(III) Tris(β-diketonate) Adducts
    Knyazev, Andrey A.
    Karyakin, Maksim E.
    Romanova, Ksenia A.
    Heinrich, Benooit
    Donnio, Bertrand
    Galyametdinov, Yuriy G.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2017, (03) : 639 - 645
  • [27] Synthesis, crystal structure and luminescent properties of new tris-β-diketonate Eu(III) complex with thiadiazolophenanthroline derivative ligand
    Gallardo, Hugo
    Conte, Gilmar
    Tuzimoto, Patricia
    Bortoluzzi, Adailton
    Peralta, Rosely A.
    Neves, Ademir
    INORGANIC CHEMISTRY COMMUNICATIONS, 2008, 11 (10) : 1292 - 1296
  • [28] A STRUCTURAL STUDY OF TRIS(BETA-DIKETONATE)EUROPIUM(III) COMPLEXES IN SOLUTION USING MAGNETIC CIRCULARLY POLARIZED LUMINESCENCE SPECTROSCOPY
    RICHARDSON, FS
    BRITTAIN, HG
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (01) : 18 - 24
  • [29] Synthesis, characterization, and luminescence of β-cyclodextrin inclusion compounds containing europium(III) and gadolinium(III) tris(β-diketonates)
    Braga, SS
    Ferreira, RAS
    Gonçalves, IS
    Pillinger, M
    Rocha, J
    Teixeira-Dias, JJC
    Carlos, LD
    JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (44): : 11430 - 11437
  • [30] Circularly polarized red luminescence based on new enantiopure menthol-functionalized tris-β-diketonate-Eu3+ binary complexes
    Liu, Jiaxiang
    Guo, Yanan
    Qu, Fan
    Lin, Lei
    Yao, Sicheng
    Yuan, Chunmei
    Zhang, Zhiming
    Zhao, Yuzhen
    Lue, Xingqiang
    JOURNAL OF LUMINESCENCE, 2025, 281