The stereospecific addition of hydroxylamines to α,β-unsaturated sulfones, nitriles and nitro compounds

被引：16
|
作者：
O'Neil, IA
Cleator, E
Southern, JM
Bickley, JF
Tapolczay, DJ
机构：
[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England
[2] Millennium Pharmaceut, Merryfield Ctr, Cambridge CB1 3LQ, England
来源：
TETRAHEDRON LETTERS | 2001年 / 42卷 / 46期
基金：
英国工程与自然科学研究理事会;
关键词：
D O I：
10.1016/S0040-4039(01)01746-4
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
N-Alkyl hydroxylamines have been shown to undergo a highly stereospecific cis addition to alpha,beta -unsaturated sulfones, nitriles and nitro compounds. (C) 2001 Published by Elsevier Science Ltd.
引用
收藏
页码：8251 / 8254
页数：4
相关论文
共 50 条
  • [11] ALPHA ADDITION OF HYDROXYLAMINES TO ISOCYANIDE COMPOUNDS
    ZINNER, G
    HEUER, W
    MODERHAC.D
    CHEMIKER-ZEITUNG, 1974, 98 (03): : 159 - 159
  • [12] Addition of secondary amines to α,β-unsaturated carbonyl compounds and nitriles by using microstructured reactors
    Loewe, H.
    Hessel, V.
    Loeb, P.
    Hubbard, S.
    ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2006, 10 (06) : 1144 - 1152
  • [13] Addition of organotin anions to α,β-unsaturated nitriles
    Lassalle, V
    Lockhart, MT
    Chopa, AB
    MOLECULES, 2000, 5 (03) : 391 - 392
  • [14] Addition, elimination, exchange, and epimerization in nitro sulfones
    Kingsbury, Charles A.
    Weinhold, Jon
    Winter, Jeremy
    JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 2007, 20 (03) : 161 - 166
  • [15] THE STRUCTURE OF LITHIUM COMPOUNDS OF SULFONES, SULFOXIMIDES, SULFOXIDES, THIOETHERS AND 1,3-DITHIANES, NITRILES, NITRO-COMPOUNDS AND HYDRAZONES
    BOCHE, G
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (03): : 277 - 297
  • [16] DIRECT TRANSFORMATION OF PRIMARY NITRO-COMPOUNDS INTO NITRILES - NEW SYNTHESES OF ALPHA,BETA-UNSATURATED NITRILES AND CYANOHYDRIN ACETATES
    WEHRLI, PA
    SCHAER, B
    JOURNAL OF ORGANIC CHEMISTRY, 1977, 42 (24): : 3956 - 3958
  • [17] KINETICS OF BROMINE ADDITION TO SOME UNSATURATED SULFONES
    BALIAH, V
    SHANMUGANATHAN, S
    JOURNAL OF PHYSICAL CHEMISTRY, 1959, 63 (12): : 2016 - 2018
  • [18] Enantioselective Conjugate Addition of Nitro Compounds to α,β-Unsaturated Ketones: An Experimental and Computational Study
    Manzano, Ruben
    Andres, Jose M.
    Alvarez, Rosana
    Muruzabal, Maria D.
    de Lera, Angel R.
    Pedrosa, Rafael
    CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (21) : 5931 - 5938
  • [19] Asymmetric conjugate addition of azide to α,β-unsaturated nitro compounds catalyzed by cinchona alkaloids
    Nielsen, Martin
    Zhuang, Wei
    Jorgensen, Karl Anker
    TETRAHEDRON, 2007, 63 (26) : 5849 - 5854
  • [20] UNSATURATED NITRO-COMPOUNDS
    PEREKALIN, VV
    ZHURNAL ORGANICHESKOI KHIMII, 1985, 21 (05): : 1111 - 1128
12345