Anodic polarization behavior of copper in propylene carbonate

被引：29
|
作者：
Kawakita, J
Kobayashib, K
机构：
[1] Natl Res Inst Met, Tsukuba, Ibaraki 3050047, Japan
[2] Keio Univ, Fac Sci & Technol, Dept Chem, Kouhoku Ku, Yokohama, Kanagawa 2238522, Japan
来源：
JOURNAL OF POWER SOURCES | 2001年 / 101卷 / 01期
关键词：
copper; propylene carbonate; corrosion; FE-SEM; EQCM;
D O I：
10.1016/S0378-7753(01)00555-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Anodic polarization behavior of copper in propylene carbonate was investigated using electrochemical measurements, microscopic observations, elemental and gravimetric analyses. These results exhibited that anodic polarization of copper brought about oxidative dissolution of the metal substrate in competition with decomposition of the electrolyte on the metal surface. A reaction mechanism for oxidative dissolution was proposed with respect to both the charge transferring and the geometric form. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：47 / 52
页数：6
相关论文
共 50 条
  • [21] ANODIC BEHAVIOR OF COPPER IN HCL
    IBL, N
    MULLER, R
    COOPER, RS
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1955, 102 (06) : 361 - 361
  • [22] ANODIC-OXIDATION OF MERCURY IN THE PRESENCE OF MONOCYCLIC LIGANDS IN PROPYLENE CARBONATE
    BOUDON, C
    GISSELBRECHT, JP
    GROSS, M
    HOSSEINI, MW
    ELECTROANALYSIS, 1989, 1 (06) : 493 - 499
  • [23] ANODIC-DISSOLUTION OF NICKEL IN PROPYLENE CARBONATE CONTAINING LITHIUM SALT
    NAKAJIMA, T
    MATSUZAKA, E
    TSURU, T
    DENKI KAGAKU, 1990, 58 (07): : 667 - 669
  • [24] ANODIC POLARIZATION BEHAVIOR OF AN AMORPHOUS METAL
    DEVINE, TM
    WELLS, L
    SCRIPTA METALLURGICA, 1976, 10 (04): : 309 - 310
  • [25] THE BEHAVIOR OF CHROMIUM ON CATHODIC AND ANODIC POLARIZATION
    ISSA, IM
    AMMAR, IA
    KHALIFA, H
    JOURNAL OF PHYSICAL CHEMISTRY, 1955, 59 (06): : 492 - 495
  • [26] Oxidative carbonylation of propylene glycol to propylene carbonate by copper-based catalysts
    Yang, Pao -Chi
    Lee, Yen-Te
    Tsai, Yi-Ta
    Huang, Chien -Fu
    Pan, Yung -Tin
    Tsai, De-Hao
    JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2024, 158
  • [27] BEHAVIOR OF CERTAIN INDICATORS IN PROPYLENE CARBONATE MEDIUM
    NEDVETSKAYA, GB
    SHEVTSOVA, IY
    BARANOV, NA
    JOURNAL OF ANALYTICAL CHEMISTRY OF THE USSR, 1985, 40 (04): : 516 - 520
  • [28] Catalytic behavior of calcium oxide for synthesis of dimethyl carbonate from propylene carbonate from propylene carbonate and methanol.
    Wei, T
    Wei, W
    Wang, MH
    Sun, Y
    Zhong, B
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 223 : U584 - U584
  • [29] REDOX BEHAVIOR OF "HEXAKISMETHYLISONITRILEMANGANESE(I) IN PROPYLENE CARBONATE
    GRITZNER, G
    MONATSHEFTE FUR CHEMIE, 1976, 107 (05): : 1055 - 1064
  • [30] BEHAVIOR OF HYDROGEN AND GLASS ELECTRODES IN PROPYLENE CARBONATE
    TALARMIN, J
    LHER, M
    COURTOTCOUPEZ, J
    COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES SERIE C, 1978, 287 (04): : 105 - 108
12345