Preparation of polyaniline in organic liquid crystal solvent

被引：2
|
作者：
Miyashita, Ryo [1 ]
Goto, Hiromasa [1 ]
机构：
[1] Univ Tsukuba, Grad Sch Pure & Appl Sci, Dept Mat Sci, Tsukuba, Ibaraki 3058573, Japan
来源：
MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2022年 / 738卷 / 01期
基金：
日本学术振兴会;
关键词：
Cholesteric liquid crystal; new polymerization method; polyaniline; SPIN-RESONANCE ABSORPTION; POLYMERIZATION; METALS;
D O I：
10.1080/15421406.2021.2017104
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Polyaniline (PANI) is generally prepared in a water medium. However, a new method for the synthesis of PANI in an organic solvent was developed in this study. PANI was successfully synthesized in an organic cholesteric liquid crystal (CLC) matrix using ammonium peroxodisulfate and 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) as two initiators to progress the polymerization. Polymerization in the CLC matrix resulted to PANI with an ordered structure due to secondary doping in the monomer propagation process.
引用
收藏
页码：1 / 7
页数：7
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