Methanol Steam Reforming in Membrane Reactors

被引：17

作者：

Lytkina, A. A. ^{[1
]}

Orekhova, N. V. ^{[1
]}

Yaroslavtsev, A. B. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Topchiev Inst Petrochem Synth, Moscow 119991, Russia

[2] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

来源：

PETROLEUM CHEMISTRY | 2018年 / 58卷 / 11期

关键词：

hydrogen; steam reforming of methanol; metallic membranes; palladium membranes; membrane reactor; catalysis; hydrogen energy; EFFICIENT HYDROGEN-PRODUCTION; PACKED-BED REACTORS; GAS SHIFT REACTION; SELECTIVE MEMBRANES; PARTIAL OXIDATION; CARBON-MONOXIDE; FUEL PROCESSOR; MICRO-MEMBRANE; H-2; PRODUCTION; NATURAL-GAS;

D O I：

10.1134/S096554411811004X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A brief review of recent scientific publications concerning the steam reforming of methanol in membrane reactors for the production of pure hydrogen is presented. The use of membrane reactors makes it possible to lower the temperature of this process by 100 degrees C, increase the selectivity of the process, and practically eliminate the effect of catalysts' carbonization. A substantial advantage of the use of membrane reactors is the possibility for removing a stream of high-purity hydrogen from the permeate zone. First of all, this applies to CO impurities, whose presence is critical for the use of hydrogen in low-temperature fuel cells based on proton-conducting membranes. The use of metallic membranes based on Pd makes it possible to directly use the hydrogen produced in the fuel cells.

引用

页码：911 / 922

页数：12

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