A morphotropic phase boundary system based on polarization rotation and polarization extension

被引：564
|
作者：
Damjanovic, Dragan [1 ]
机构：
[1] Ecole Polytech Fed Lausanne, Swiss Fed Inst Technol Lausanne, Ceram Lab, CH-1015 Lausanne, Switzerland
来源：
APPLIED PHYSICS LETTERS | 2010年 / 97卷 / 06期
基金：
瑞士国家科学基金会;
关键词：
dielectric polarisation; ferroelectric transitions; phase diagrams; FERROELECTRIC SINGLE-CRYSTALS; SOLID-SOLUTION SYSTEMS; PIEZOELECTRIC PROPERTIES; OXIDE FERROELECTRICS; MONOCLINIC PHASE; ELECTRIC-FIELD; PEROVSKITE; CERAMICS; ENHANCEMENT; TRANSITION;
D O I：
10.1063/1.3479479
中图分类号：
O59 [应用物理学];
学科分类号：
摘要：
Many ferroelectric solid solutions exhibit enhanced electromechanical properties at the morphotropic boundary separating two phases with different orientations of polarization. The mechanism of properties enhancement is associated with easy paths for polarization rotation in anisotropically flattened free energy profile. Another mechanism of properties enhancement related to free energy flattening is polarization extension. It is best known at temperature-driven ferroelectric-paraelectric phase transitions and may lead to exceedingly large properties. Its disadvantage is temperature instability of the enhancement. In this paper a temperature-composition phase diagram is proposed that exhibits compositionally driven-phase transitions with easy paths for both polarization rotation and polarization extension. (C) 2010 American Institute of Physics. [doi:10.1063/1.3479479]
引用
收藏
页数：3
相关论文
共 50 条
  • [21] Analysis of switching in perovskite ferroelectrics on the tetragonal side of the morphotropic phase boundary using a Landau-theory-based lattice model with polarization vector rotations
    Ricinschi, D
    Ishibashi, Y
    Iwata, M
    Okuyama, M
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2001, 40 (08): : 4990 - 4997
  • [22] Dynamic polarization rotation and vector field steering based on phase change metasurface
    He, Hairong
    Yang, Hui
    Xie, Zhenwei
    Yuan, Xiaocong
    FRONTIERS OF PHYSICS, 2023, 18 (01)
  • [23] Analysis of switching in perovskite ferroelectrics on the tetragonal side of the morphotropic phase boundary using a Landau-theory-based lattice model with polarization vector rotations
    Ricinschi, Dan
    Ishibashi, Yoshihiro
    Iwata, Makoto
    Okuyama, Masanori
    2001, Japan Society of Applied Physics (40):
  • [24] Theory of the morphotropic phase boundary
    Ishibashi, Y
    FERROELECTRICS, 2002, 267 : 191 - 199
  • [25] CHARACTERISTIC FEATURES OF DIELECTRIC POLARIZATION OF FERROELECTRIC SOLID SOLUTIONS WITH PEROVSKITE-TYPE STRUCTURE AT MORPHOTROPIC PHASE BOUNDARY AND FAR FROM IT
    STOLYPIN, YE
    ISUPOV, VA
    SOVIET PHYSICS SOLID STATE,USSR, 1969, 11 (03): : 674 - &
  • [26] Direct evidence of magnetization rotation at the ferromagnetic morphotropic phase boundary in Tb1-xDyxFe2 system
    Ke, Xiaoqin
    Zhou, Chao
    Tian, Ben
    Matsushita, Yoshitaka
    Ren, Xiaobing
    Yang, Sen
    Wang, Yunzhi
    PHYSICAL REVIEW B, 2023, 108 (22)
  • [27] Very high remnant polarization and phase-change electromechanical response of BiFeO3-PbTiO3 at the multiferroic morphotropic phase boundary
    Amorin, H.
    Correas, C.
    Ramos, P.
    Hungria, T.
    Castro, A.
    Alguero, M.
    APPLIED PHYSICS LETTERS, 2012, 101 (17)
  • [28] Theory of the morphotropic phase boundary
    Ishibashi, Y
    FERROELECTRICS, 2001, 264 (1-4) : 1855 - 1864
  • [29] Chemical control of polarization in thin strained films of a multiaxial ferroelectric: Phase diagrams and polarization rotation
    Morozovska, Anna N.
    Eliseev, Eugene A.
    Biswas, Arpan
    Shevliakova, Hanna V.
    Morozovsky, Nicholas V.
    Kalinin, Sergei V.
    PHYSICAL REVIEW B, 2022, 105 (09)
  • [30] Morphotropic phase boundary in the BNT-BT-BKT system
    Trelcat, Jean-Francois
    Courtois, Christian
    Rguiti, Mohamed
    Leriche, Anne
    Duvigneaud, Paul-Henri
    Segato, Tiriana
    CERAMICS INTERNATIONAL, 2012, 38 (04) : 2823 - 2827
12345