Enantioselective addition of diethylzinc to aldehydes catalyzed by a β-amino alcohol derived from (+)-3-carene

被引：40

作者：

Joshi, SN ^{[1
]}

Malhotra, SV ^{[1
]}

机构：

[1] New Jersey Inst Technol, Dept Chem & Environm Sci, Newark, NJ 07102 USA

来源：

TETRAHEDRON-ASYMMETRY | 2003年 / 14卷 / 13期

关键词：

D O I：

10.1016/S0957-4166(03)00347-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A (+)-3-carene derived aminoalcohol was successfully used as a chiral ligand in the catalytic enantioselective diethylzinc addition to various aldehydes. Very high enantiomeric excess (up 98% in 1-(2-methoxyphenyl)-1-propanol) was obtained. A plausible mechanism has been suggested for the observed enantio selectivity. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：1763 / 1766

页数：4

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