TEX-4,10-Dinitro-2,6,8,12-tetraoxa-4,10-diazatetracyclo[5.5.0.05,9.03,11]-dodecane - Review of a Promising High Density Insensitive Energetic Material

被引:48
|
作者
Koch, Ernst-Christian [1 ,2 ]
机构
[1] Cranfield Univ, Swindon SN6 8LA, Shrivenham, England
[2] Def Acad Unted Kingdom, Ctr Def Chem, Swindon SN6 8LA, Shrivenham, England
关键词
Explosives; 4,10-Dinitro-2,6,8,12-tetraoxa-4,10-diazatetracyclo[5.5.0.0(5,9)0(3,11)]-dodecane; Insensitive munitions; TEX; Synthesis; BASE-CATALYZED REACTIONS; GLYOXAL; RDX; EXPLOSIVES; KINETICS; TEX;
D O I
10.1002/prep.201400195
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The title compound 4,10-dinitro-2,6,8,12-tetraoxa-4,10-diazatetracyclo[5.5.0.0(5,9)0(3,11)]-dodecane - often referred to as TEX - is a very promising newcomer in the field of insensitive explosives. It is easily synthesized with good yield from cheap starting materials. TEX offers a respectable high ambient temperature crystal density (1.985 g cm(-3)) and hence good detonation velocity and pressure but is fairly insensitive towards mechanical and thermal stimuli. It has a large critical diameter and is advantageously used in large charges. 76 references to the public domain are given.
引用
收藏
页码:374 / 387
页数:14
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