4,10-dinitro-2,6,8,12-tetraoxa-4,10-diazaisowurtzitane (TEX):: a nitramine with an exceptionally high density

被引:46
|
作者
Karaghiosoff, K
Klapötke, TM
Michailovski, A
Holl, G
机构
[1] Univ Munich, Dept Chem, D-81377 Munich, Germany
[2] Wehrwissensch Inst Werk Explos & Betriebsstoffe, Grosses Cent, D-53913 Swisttal, Germany
关键词
Close-packed lattices;
D O I
10.1107/S0108270102014774
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound (systematic name: 4,10-dinitro-2,6,8,12-tetraoxa-4,10-diazatetracyclo[5.5.0.0(3,11).0(5,9)]dodecane), C6H6N4O8, exhibits the highest density among known N-nitramines, due to its close-packed crystal structure. It may be regarded as consisting of a distorted hexagonal close-packed lattice formed by the isowurtzitane cages, with the nitro groups occupying the free space between the cages.
引用
收藏
页码:O580 / O581
页数:2
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