Synthesis and steric structure of triethylammonium 4,4-bis(trifluoromethyl)-2,5-dioxo-6,7-benzo-1,3,2λ5-dioxaphosphepin-2-olate

被引：0
|
作者：
Mironov, VF [1 ]
Burnaeva, LM
Gubaidullin, AT
Brazhnikova, IA
Litvinov, IA
Romanov, SV
Konovalova, IV
机构：
[1] Kazan VI Lenin State Univ, Kazan 420008, Russia
[2] Russian Acad Sci, Kazan Res Ctr, Arbuzov Inst Organ & Phys Chem, Kazan, Tatarstan, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2000年 / 70卷 / 10期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of 2-tert-butoxy-5,6-benzo-1,3,2-dioxaphosphorin-4-one with hexafluoroacetone involves ring expansion to give a 6,7-benzo-1,3,2-dioxaphosphepine with partial preservation of the tert-butoxy substituent on the phosphorus atom. The product was heated in ether in the presence of triethylamine to obtain triethylammonium 4,4-bis(trifluoromethyl)-2,5-dioxo-6,7-benzo-1,3,2 lambda5-dioxaphosphepin-2-olate. The steric structure of this compound was studied.
引用
收藏
页码：1539 / 1546
页数：8
相关论文
共 50 条
  • [41] SYNTHESIS OF 2-AMINO-4,4-BIS(TRIFLUOROMETHYL)-3-CYANO-1,4-DIHYDROBENZO[H]-QUINOLINE
    KOMAROV, KV
    CHKANIKOV, ND
    SEREDA, SV
    ANTIPIN, MY
    STRUCHKOV, YT
    KOLOMIETS, AF
    FOKIN, AV
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1988, 37 (08): : 1717 - 1719
  • [42] Synthesis and Applications of a Novel 3,4-Bis(2-Fluoro-5-Trifluoromethyl Phenyl)-2,5-Diphenyl Phenyl Grafted Polysiloxane Stationary Phase
    Wang, Bing
    Liu, Jingchen
    Li, Xu
    Wu, Bo
    CHROMATOGRAPHIA, 2018, 81 (08) : 1219 - 1229
  • [43] Synthesis and Applications of a Novel 3,4-Bis(2-Fluoro-5-Trifluoromethyl Phenyl)-2,5-Diphenyl Phenyl Grafted Polysiloxane Stationary Phase
    Bing Wang
    Jingchen Liu
    Xu Li
    Bo Wu
    Chromatographia, 2018, 81 : 1219 - 1229
  • [44] 1,3,2(1,4,2)-Dioxaphosphepins annelated with naphthalene fragment: Synthesis and steric structure
    Burnaeva, L. M.
    Mironov, V. F.
    Abdrakhmanova, L. M.
    Gubaidullin, A. T.
    Musin, R. Z.
    Ivkova, G. A.
    Litvinov, I. A.
    Latypov, Sh. K.
    Balandina, A. A.
    Konovalova, I. V.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2007, 77 (04) : 538 - 552
  • [45] 1,3,2(1,4,2)-Dioxaphosphepins annelated with naphthalene fragment: Synthesis and steric structure
    L. M. Burnaeva
    V. F. Mironov
    L. M. Abdrakhmanova
    A. T. Gubaidullin
    R. Z. Musin
    G. A. Ivkova
    I. A. Litvinov
    Sh. K. Latypov
    A. A. Balandina
    I. V. Konovalova
    Russian Journal of General Chemistry, 2007, 77 : 538 - 552
  • [46] Organo-soluble polyimides:: Synthesis and polymerization of 2,2′-bis(trifluoromethyl)-4,4′,5,5′-biphenyltetracarboxylic dianhydride
    Lin, SH
    Li, FM
    Cheng, SZD
    Harris, FW
    MACROMOLECULES, 1998, 31 (07) : 2080 - 2086
  • [47] SYNTHESIS AND STRUCTURE OF 2-ETHOXY-2-OXO-3,3,4-TRIMETHYL-5-[2-ETHOXY-4H-4,4-BIS(TRIFLUOROMETHYL)-1,3,5-OXADIAZIN-6-YL]IMINO-1,4,2-DIAZAPHOSPHOLANE
    CHEKHLOV, AN
    AKSINENKO, AY
    KORENCHENKO, OV
    SOKOLOV, VB
    FOKIN, EA
    MARTYNOV, IV
    ZHURNAL OBSHCHEI KHIMII, 1990, 60 (08): : 1739 - 1745
  • [48] Synthesis and Crystal Structure of 2,5-Bis(morpholino)-3,4-bis(p-chlorophenyl)thiophene
    ZENG Run-Shenga ZOU Jian-Pinga② WANG Xiang-Shanb MO Xue-Juna LU Zhong-Ea a (Department of Chemistry
    结构化学, 2003, (03) : 279 - 282
  • [49] FORMATION OF 2,5-DIARYL-1,3-DITHIOLYL-IUM-4-OLATE IN THERMAL-REACTION OF 4-ARYL-1,3,2-OXATHIAZOLYLIUM-5-OLATE
    TONO, M
    AOTO, H
    MATSUDAIRA, Y
    SUGIYAMA, T
    KAJITANI, M
    AKIYAMA, T
    SUGIMORI, A
    TETRAHEDRON LETTERS, 1991, 32 (32) : 4023 - 4026
  • [50] Synthesis and crystal structure of 2,5-bis(morpholino)-3,4-bis(p-chlorophenyl)thiophene
    Zeng, RS
    Zou, JP
    Wang, XS
    Mo, XJ
    Lu, ZE
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2003, 22 (03) : 279 - 282
12345