A facile preparation and properties of (2E,4E,6E,8E)-1-(3-guaiazulenyl)-3,7-dimethyl-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2,4,6,8-nonatetraen-1-ylium hexafluorophosphate

被引：22
|
作者：
Nakamura, M
Sasaki, M
Takekuma, H
Minematsu, T
Takekuma, S
机构：
[1] Kinki Univ, Fac Sci & Engn, Dept Appl Chem, Osaka 5778502, Japan
[2] Kinki Univ, Sch Pharmaceut Sci, Osaka 5778502, Japan
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2003年 / 76卷 / 10期
关键词：
D O I：
10.1246/bcsj.76.2051
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reactions of guaiazulene (1) with all-trans- and 13-cis-retinals (2a and 2b) in methanol in the presence of hexafluorophosphoric acid at -10degreesC for 1h afforded the title mono-carbocation compound 3 in 87-91% yield, respectively.
引用
收藏
页码：2051 / 2052
页数：2
相关论文
共 50 条
  • [31] NMR-STUDY OF MOLECULES IN ANISOTROPIC SYSTEMS .2. 1A,2A,3E,4E,5E,6E-HEXACHLOROCYCLOHEXANES AND 1E,2E,3E,4E,5E,6E-HEXACHLOROCYCLOHEXANES DISSOLVED IN NEMATIC LIQUID-CRYSTALS
    FUJIWARA, H
    SHIMIZU, N
    TAKAGI, T
    SASAKI, Y
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1985, 58 (08) : 2285 - 2288
  • [32] ANIONOTROPIC REARRANGEMENT OF (2,4Z,7E)-3,7-DIMETHYL-9-(2,2,6-TRIMETHYL-6-CYCLOHEXEN-1-YL)-1,6-DIACETOXY-2,4,7-NONATRIENE IN ACETIC-ACID SOLUTIONS
    VYSOCHIN, AP
    DEINEKA, VI
    STAROVEROV, VM
    RUDAKOVA, NM
    SELYUKOVA, TA
    ZHURNAL ORGANICHESKOI KHIMII, 1991, 27 (09): : 1831 - 1836
  • [33] (2E)-3-(6-Methoxynaphthalen-2-yl)-1-[4(methylsulfanyl)phenyl]prop-2-en-1-one
    Fun, Hoong-Kun
    Chia, Tze Shyang
    Padaki, Mahesh
    Isloor, Arun M.
    Ismail, A. F.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O2277 - +
  • [34] Fragrance material review on 1-(2,6,6-trimethyl-2-cyclohexen-1-yl)pent-1-en-3-one
    Scognamiglio, J.
    Letizia, C. S.
    Api, A. M.
    FOOD AND CHEMICAL TOXICOLOGY, 2013, 62 : S115 - S119
  • [35] (2E)-1-(6-Chloro-2-methyl-4-phenylquinolin-3-yl)-3-(4-chlorophenyl)prop-2en-1-one
    Sarveswari, S.
    Vijayakumar, V.
    Ng, Seik Weng
    Tiekink, Edward R. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O624 - U1770
  • [36] Stereospecific preparation of (1E,3E,5E)-3.4-difluoro-1,6-diphenylhexatriene and (2E,4E,6E)-diethyl-4,5-difluoroocta-2,4,6-trienedioate
    Liu, Qibo
    Swenson, Dale C.
    Burton, Donald J.
    JOURNAL OF FLUORINE CHEMISTRY, 2011, 132 (02) : 128 - 130
  • [37] (2E,4E)-1-(3-Nitrophenyl)-5-phenylpenta-2,4-dien-1-one
    Patil, P. S.
    Teh, Jeannie Bee-Jan
    Fun, Hoong-Kun
    Razak, Ibrahim Abdul
    Dharmaprakash, S. M.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O2122 - O2123
  • [38] *SYNTHESE DER VITAMIN-A-SAURE UND DER ENTSPRECHENDEN, DEN ALPHA-JONONKOHLENSTOFFRING ENTHALTENDEN VERBINDUNG (3,7-DIMETHYL-9-[1',1',3'-TRIMETHYL-C-HEXEN-3'-YL-2']-NONATETRAEN-(2,4,6,8)-CARBONSAURE)
    KARRER, P
    JUCKER, E
    SCHICK, E
    HELVETICA CHIMICA ACTA, 1946, 29 (03) : 704 - 711
  • [39] (E)-1-(1,3,6,8-tetramethoxynaphthalen-2-yl)but-2-en-1-one
    Choudhary, MI
    Lannang, AM
    Ali, S
    Anjum, S
    Fun, HK
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O1015 - O1017
  • [40] Synthesis and Cytotoxic Evaluation of Novel 1,2,3-Triazole-4-Linked (2E,6E)-2-Benzylidene-6-(4-nitrobenzylidene)cyclohexanones
    Mahdavi, Mohammad
    Akhbari, Maryam
    Saeedi, Mina
    Karimi, Maryam
    Foroughi, Niloufar
    Karimpour-Razkenari, Elahe
    Alinezhad, Heshmatollah
    Foroumadi, Alireza
    Shafiee, Abbas
    Akbarzadeh, Tahmineh
    HELVETICA CHIMICA ACTA, 2016, 99 (03) : 175 - 180
12345