Enhancing chromium poisoning tolerance of La0.8Sr0.2Co0.2Fe0.8O3-d cathode by Ce0.8Gd0.2O1.9-d coating

Cr poisoning has been regarded as a significant reason for the degradation of La0.8Sr0.2Co0.2Fe0.8O3-delta (LSCF) cathode in practical application. In recent years, protective coating on cathode surface has been recognized as an effective approach to improve the Cr poisoning resistance of cathode. In this work, Ce0.8Gd0.2O1.9-delta (GDC) layer is successfully coated on LSCF nanoparticles by sol-gel method, endowing the GDC coated LSCF (LSCF@GDC) composite material with excellent electrochemical properties and Cr poisoning tolerance. The LSCF@GDC0.32 composite cathode exhibits a lower total impedance increase of 0.20 omega cm(2) per 200 h and 0.31 omega cm(2) per 200 h for open circuit and constant current test with SUS430 as Cr source, respectively, compared with the bare LSCF cathode (0.90 omega cm(2) per 200 h and 1.53 omega cm(2) per 200 h, respectively). In addition, according to energy dispersion spectrum (EDS) and tip enhanced Raman characterization, the enhanced Cr poisoning tolerance of composite cathode can also be verified through the alleviated SrCrO4 formation and Cr deposition on LSCF cathode.