Synthesis and characterisation of La0.6Sr0.4Co0.8Fe0.2O3-δ-Gd0.2Ce0.8O1.9 composite cathode for Gd0.2Ce0.8O1.9 electrolyte SOFC

被引:1
|
作者
Cheng, J. [1 ]
Tian, C.
Zhu, R. [2 ]
机构
[1] Hefei Univ Technol, Sch Chem Engn, Hefei 230009, Peoples R China
[2] Hefei Univ, Dept Chem & Mat Engn, Hefei 230601, Peoples R China
基金
中国国家自然科学基金;
关键词
Composite cathode; Solid oxide fuel cell; Electrochemical property; LSCF; CGO; OXIDE FUEL-CELL; PERFORMANCE; REDUCTION; IMPEDANCE;
D O I
10.1179/1433075X13Y.0000000194
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A high performance composite cathode, La0.6Sr0.4Co0.8Fe0.2O3-delta-Gd0.2Ce0.8O1.9 (LSCF-CGO), was synthesised for intermediate temperature solid oxide fuel cell. The effect of CGO incorporation on the electrical properties was studied by electrochemical impedance spectroscopy. The results show that the LSCF-CGO composite cathode shows better electrochemical performance with maximum power densities of 88 mW cm(-2) at 800 degrees C. The improved performance of LSCF-CGO is attributed to the extended triple phase boundary and enhanced oxide ion conductivity.
引用
收藏
页码:461 / 464
页数:4
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