(2,2′-Bipyridine-κ2N,N′)dichlorido(dimethyl sulfoxide-κO)zinc(II)

被引:5
|
作者
Marjani, Katayoun
Mousavi, Mohsen
Khavasi, Hamid Reza
Ansari, Maryam
Qumi, Hamid Reza
机构
[1] Teacher Training Univ, Fac Chem, Tehran 15614, Iran
[2] Shaheed Beheshti Univ, Dept Chem, Tehran, Iran
关键词
D O I
10.1107/S1600536807047320
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [ZnCl2(C10H8N2)(C2H6OS)],the Zn atom is five-coordinate, forming a distorted trigonal-bipyramidal geometry involving one Cl atom, one dimethyl sulfoxide O atom and one 2,2'-bipyridine N atom in equatorial positions, with distances Zn - Cl = 2.2863 (7) angstrom, Zn - O = 2.1024 (15) angstrom and Zn - N = 2.1546 (16) angstrom. The axial positions are occupied by the other 2,2'-bipyridine N atom and a Cl atom, with distances N - Zn = 2.1604 (16) angstrom and Zn - Cl = 2.3123 (7) angstrom
引用
收藏
页码:M2645 / U187
页数:9
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